磷矿中伴生的微量稀土作为一种潜在的稀土资源,开展综合回收稀土的研究具有重要意义.简单介绍了磷矿中稀土含量及分布状况,综述了磷化工过程中回收稀土的最新研究进展,分别介绍了回收稀土的方法及现状,对未来磷矿中微量稀土提取技术研究方向进行了探讨.
参考文献
| [1] | 程春.矾山磷铁矿床稀土元素地球化学特征[J].化工矿产地质,2001(02):104-108. |
| [2] | 徐光宪.稀土[M].北京:冶金工业出版社,1978:107. |
| [3] | 金会心,王华,李军旗.新华戈仲伍组含稀土磷块岩矿石性质研究[J].稀有金属,2007(03):377-383. |
| [4] | 鲁如坤.我国的磷矿资源和磷肥生产消费Ⅰ.磷矿资源和磷肥生产[J].土壤,2004(01):1-4,11. |
| [5] | 刘代俊,蒋绍志,罗洪波,张允湘.我国磷矿资源贫化趋势与对策探讨[J].磷肥与复肥,2005(01):6-9. |
| [6] | 姚永发;方天翰.磷酸磷铵重钙技术与设计手册[M].北京:化学工业出版社,1997 |
| [7] | 施春华,胡瑞忠,王国芝.贵州织金磷矿岩稀土元素地球化学特征研究[J].矿物岩石,2004(04):71-75. |
| [8] | 张杰,张覃,陈代良.贵州织金新华含稀土磷矿床稀土元素地球化学研究[J].地质与勘探,2004(01):41-44. |
| [9] | 张杰,张覃,陈代良.贵州织金新华含稀土磷矿床稀土元素地球化学及生物成矿基本特征[J].矿物岩石,2003(03):35-38. |
| [10] | Mohamed Krea;Hussein Khalaf .Liquid-liquid extraction of uranium and lanthanides from phosphoric acid using a synergistic DOPPA-TOPO mixture[J].Hydrometalinrgy,2000,58:215. |
| [11] | Koopman C.;Witkamp G.J. .Extraction of lanthanides from the phosphoric acid production process to gain a purified gypsum and a valuable lanthanide by-product[J].Hydrometallurgy,2000(1):51-60. |
| [12] | 伍沅.磷矿综合利用提取稀土述评[J].武汉化工学院学报,1983(01):1-13. |
| [13] | 王华,洪业汤,朱咏煊,易丽.黄磷生产中的稀土元素分布[J].稀土,2002(04):25-28. |
| [14] | 毛常明,刘晶晶,尹进华,陈学玺.湿法磷酸的工艺研究进展[J].河北化工,2005(04):14-16,36. |
| [15] | 马步真.硝酸磷肥的现状与发展之我见[J].硫磷设计与粉体工程,2002(02):9-12. |
| [16] | Monir M My;Nabawia A Mohammed .Recovery of lanthanides from Abu Tartur phosphate rock,Egypt[J].Hydrometallurgy,1999,52:199. |
| [17] | Li Junqi;Jin Huixin;Wang Hua.Rare earth elements in Zhijin phosphorite and distribution in two-stage flotation process[A].Baoton,China:August,2007:88. |
| [18] | Mejdell Gler Torvall;Steren Kharald .Method of extracting rare earth elements from apatite[P].SU764607,1980. |
| [19] | Zimirna Galinav;Glubokova Tatyanan .Method of extraction rare earth metals from apatite[P].SU1636337,1991. |
| [20] | Glubokova Tatyanan;Zimina Galinav .Method of recovering rare earth metals from apatite[P].SU1736933,1992. |
| [21] | Bolkov Aleksandr Fedorovich;Gritsaeva Antonina Mikhajlovna .Method for recovery rare earth elements of apatite[P].RU2049727,1995. |
| [22] | 李德谦;李红飞;董高翔;王忠怀 .一种从磷灰石中提取稀土的方法[P].CN1257290C,2006. |
| [23] | Slack A V.Phosphoric Acid[M].New York,USA:Marcel Dekker,Inc,1968 |
| [24] | 陕西省化工设计研究院研究室稀土富集专题组.以唐渡磷矿富集稀土并制沉淀磷酸钙小试验报告[J].应用化工,1977(02):12. |
| [25] | 王光宙;牛新书;赵春霞;张应桂,王剑平.以豫南磷矿富集稀土并制饲钙的研究[J].无机盐工业,1997(04):6. |
| [26] | 姚鼎文;王昌慧 .盐酸分解磷矿制备磷酸盐及磷酸的方法[P].CN85102768 |
| [27] | 赵廷仁;刘建清;尹其光.湿法磷酸精制技术的现状与进展[J].化工进展,1992(02):45. |
| [28] | Koopman C;Witkamp G J.Ion exchange extraction during continuous recrystallization of in the phosphoric acid production process:lanthanidc CaSO4 extraction efficiency and CaSO4 particle shape[J].Hydrometalinrgy,2000(2002):1. |
| [29] | 齐焉.2004年全国硫酸磷肥生产情况[J].硫酸工业,2005(02):11-14. |
| [30] | Jarosinski A;Kowalczyk J;Mazanek Cz .Development of the Polish wasteless technology of apatite phosphogypsum utilization with recovery of rare earths[J].Journal of Alloys and Compounds,1993,200:147. |
| [31] | Preston J S;Cole P M;Craig WM;Feather AM .The recovery of rare earth oxides from a phosphoric acid by-product[J].Hydrometallurgy,1996,41:1. |
| [32] | Skorovarov J I;Kosynkin V D;Moiseev S D;Rura N N .Recovery of rare earth elements from phosphoritos in the USSR[J].Journal of Alloya and Compounds,1992,180:71. |
| [33] | 路坊海 .织金含稀土磷矿石浮选及浸出工艺的研究[D].贵州大学,2006. |
| [34] | 龙志奇;黄小卫;王良士;彭新林,韩业斌,崔大立 .一种从磷矿中富集回收稀土的方法[P].200710178377.6 |
| [35] | 王良士,龙志奇,黄小卫,彭新林,韩业斌,崔大立.湿法磷酸生产过程中控制稀土走向的研究[J].中国稀土学报,2008(03):307-312. |
| [36] | 陈家镛.湿法冶金手册[M].北京:冶金工业出版社,2005:1002. |
| [37] | Lokshin EH P;Vershkova JU A;Kalinaikov V T .Method of recovering rare-earth minerals from phosphogypsum[P].RU2225892,2004. |
| [38] | Lededev V N;Lokshin EH P .Method of isolation of rare-earth elements from phosphogypeum[P].RU2158317,2000. |
| [39] | Lededev V N;Sergeeva S D .Method of processing phosphaterare-earth concentrate isolated from apatite[P].RU2148019,2000. |
| [40] | Lededev V N;Masloboev V A;Lokshin Eh P;Popova L A Sergeera S D .Method d extraction of rare-earth element phosphates from apatite concentrate[P].RU2120408,1998. |
| [41] | Pessac Jean Fava;Puisenx Andre Lambert;La Rochelle;JeanPaul Tognet .Essentially complete recovery of uranium,yttrium,thorium and rare earth values from phosphate rock during wet-process production of phosphoric acid therefrom[P].US4636369,1987. |
| [42] | 曾繁瑞.磷矿中的稀土回收探讨[J].云南化工,1998(02):59. |
| [43] | Hurst F J;Crouse D J;Brown K B .Solvent Extraction of Uranium From Wet-Process Phosphoric Acid[Report ORNLTM-2522][R].Oak Ridge National Laboratory,1969. |
| [44] | Hurst F J;Crouse D J;Brown K B .Recovery of uranium from wet-procoss phosphoric acid[J].Industrial & Engineering Chemistry:Process Design and Development,1972,11(01):122. |
| [45] | Hurst F J;Crouse D J .Reductive stripping process for the recovery of uranium from wet-process phosphoric acid[P].U.S.3711591,1973. |
| [46] | Richelton W A .Recovery of uranium from wet process phosphoric acid using assymetrical phesphine oxides[P].U.S.4778663,1988. |
| [47] | Bunu F;Dumitreacu R .Simultaneous extraction of rare earth elements and uranium from phosphoric acid[J].Hydrometallurgy,1992,28(03):331. |
| [48] | Bunu F;Miu I;Dumitrescut R.Simultaneous recovery and separetion of uranium and rare earths from phosphoric acid in a onecycl extraction-stripping process[J].Hydrometallurgy,1994(35):375. |
| [49] | Harvinderpol Singh;Mishm S L;Vijayalakshmi R.Uranium recovery from phosphoric acid by solvent extraction using a synergistic mixture of di-nonyl phenyl phosphoric acid and tri-n-butyl phosphate[J].Hydrometsllurgy,2004(73):63. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%