欢迎登录材料期刊网

材料期刊网

高级检索

VGF技术生长单晶时温度梯度较低,生长速率较小.目前已成为生长大直径、低位错密度晶体的主流技术之一.采用数值模拟研究了VGF法6英寸低位错Ge单晶的生长,结果表明在采用自主研发的VGF炉生长6英寸Ge单晶时,晶体生长过程中晶体与熔体中均具有较低的温度梯度(这里的温度梯度是指的界面附近的温度梯度),尤其当晶体生长进入等径生长阶段后,晶体中的轴向温度梯度在2-3K·cm-1之间,熔体中的轴向温度梯度0.8-1.0 K·cm-1之间;晶体中的热应力除边缘外均在(2-9)x10~4 Pa之间,低于Ge单晶的临剪切应力,且晶体生长界面较平整;坩埚与坩埚托之间的间隙对于晶体生长中的"边界效应"影响显著,将8mm间隙减小至2 mm后,埚壁外侧的径向热流增加,使得晶体边缘的最大热应力减小至0.21 MPa和Ge单晶的临剪切应力相当,实现了热场的优化.

参考文献

[1] Jordan A S;Monberg E M;Clemans J E .Thermal stress theory of dislocation reduction in the vertical gradient freeze(VGF)growth of GaAs and InP[J].Journal of Crystal Growth,1993,128:444.
[2] Monberg E M;Gault W A;Simchock F;Dominguez F .Verti-cal gradient freeze growth of large diameter,low defect density in-dium phosphide[J].Journal of Crystal Growth,1987,83:174.
[3] Fahey R E;Strauss A J;Anderson A C .Vertical gradient-freeze growth of aluminate crystals[J].Journal of Crystal Growth,1993,128:672.
[4] Yasunori Okano;Hiroki Kondo;Wataru Kishimoto .Experimental and numerical study of the VGF growth of CdTe crystal[J].Journal of Crystal Growth,2002(Pt.3):1716-1719.
[5] Garandet J P;Duffer T;Favier J J .Vertical gradient freeze growth and characterization of high quality GaSb single crystals[J].Journal of Crystal Growth,1989,96:888.
[6] Dieter Hofmann;Thomas Jung;Georg Muller .Growth of 2 inch Ge:Ga crystals by the dynamical vertical gradient freeze process and its numerical modelling including transient segregation[J].Journal of Crystal Growth,1993,128:213.
[7] Bellmann M P;Ptttzold O;Gtirtner G;Mtiller H J,Stelter M .Radial segregation in VGF-RMF grown germanium[J].Journal of Crystal Growth,2009,311:1471.
[8] Frank-Rotsch Ch;Rudolph P .Vertical gradient freeze of 4 inch Ce crystals in a heater-magnet module[J].Journal of Crystal Growth,2009,311:2294.
[9] Langheinrich D;Pgtzold O;Raabe L;Stelter M .VGF growth of germanium single crystals without crucible contact[J].Journal of Crystal Growth,2010,312:2291.
[10] Patzold O;Jenkner K;Scholz S;Croll A .Detached growth behaviour of 2-in germanium crystals[J].Journal of Crystal Growth,2005(1/4):37-43.
[11] Palosz W;Volz M;Cobb S;Motakef S;Szofran FR .Detached growth of germanium by directional solidification[J].Journal of Crystal Growth,2005(1/4):124-132.
[12] 丁国强,苏小平,屠海令,张峰燚
[13] Smimov Yu M;Kaplunov I A;Dolmatov A B .Dislocation gen-eration in dislocation-free germanium[J].Russian Physics Journal,2005,48:460.
[14] Jasinski T;Witt A F .On control of the crystal-melt interface shape during growth in a vertical Bridgman configuration[J].Journal of Crystal Growth,1985,71:295.
[15] Koai K;Sonnenherg K;Wenzl H .Influence of crucible support and radial heating on the interface shape during vertical Bridgman GaAs growth[J].Journal of Crystal Growth,1994,137:59.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%