欢迎登录材料期刊网

材料期刊网

高级检索

粘结剂原料钴粉在制备超细晶WC-Co硬质合金中的作用至关重要.采用超细/纳米级粒度的球形钴粉不仅可以降低合金的烧结致密化温度从而抑制WC晶粒异常长大,同时能够减少球磨混合时间、改善合金中的钴相分布,有助于获得高性能的超细和纳米晶WC-Co硬质合金.总结了近年来超细和纳米晶WC-Co硬质合金用钴粉的国内外研究开发状况,介绍了采用液相沉淀-氢还原法制备球形纳米钴粉的取得的实验成果,指出该法是生产超细和纳米晶WC-Co硬质合金用纳米钴粉的一种行之有效的新工艺路线.

参考文献

[1] 邵刚勤,吴伯麟,魏明坤,袁润章.超细晶粒WC硬质合金的研制动态[J].武汉工业大学学报,1999(06):18-20.
[2] 邬荫芳.“双高”超细合金的研制[J].硬质合金,2000(04):214-20.
[3] 吴恩熙,雷贻文.超细硬质合金中晶粒生长抑制剂的作用[J].硬质合金,2002(03):136-139.
[4] Z. FANG;J. W. EASON .Study of Nanostructured WC-Co Composites[J].International Journal of Refractory Metals & Hard Materials,1995(5):297-303.
[5] 朱丽慧,马学鸣,雷景轩,赵海锋.纳米硬质合金的研究进展[J].稀有金属材料与工程,2004(04):349-353.
[6] 林晨光.中国超细晶粒WC-Co硬质合金研究进展[J].稀有金属,2004(04):762-766.
[7] Brookes K .Some tribulation on the way to a nano future for hardmetals[J].Metal Powder Report,2005,60(12):24.
[8] 林晨光.中国超细和纳米晶WC-Co硬质合金的研究开发概况[J].中国钨业,2005(02):19-23.
[9] 罗骥 .超细晶粒WC-Co制备技术及晶粒长大抑制机理研究[D].北京:北京科技大学,2007.
[10] W. D. SCHUBERT;A. BOCK;B. LUX .General Aspects and Limits of Conventional Ultrafine WC Powder Manufacture and Hard Metal Production[J].International Journal of Refractory Metals & Hard Materials,1995(5):281-296.
[11] Goren-Muginstein G R;Berger S;Rosen A .Sintering study of nanocrystalline tungsten carbide powder[J].Nanestructured Materials,1998,10(05):795.
[12] Michael Sommer;Wolf-Dieter Schubert;Erich Zobetz .On the formation of very large WC crystals during sintering of ultrafine WC-Co alloys[J].International Journal of Refractory Metals & Hard Materials,2002(1):41-50.
[13] A. Adorjan;W.D. Schubert;A. Schon .WC grain growth during the early stages of sintering[J].International Journal of Refractory Metals & Hard Materials,2006(5):365-373.
[14] Fang Z;Maheshwari P;Wang X;Sohn H Y Griffo A Riley R .An experimental study of the sintering of nanocrystalline WC-Co powders[J].International Journal of Refractory Metals and Hard Materials,2005,23(4-6):249.
[15] 张忠健,汪晓,李仁琼,胡茂中.中国硬质合金产业的技术进步[J].硬质合金,2007(01):33-38.
[16] Shi X L;Shao G Q;Duan X L;Xiong Z Yang H .Characterizations of WC-10Co nanocomposite powders and subsequently sinterhip sintered cemented carbide[J].Materials Characterization,2006,57(4-5):358.
[17] Azcona I.;Ordonez A.;Sanchez JM.;Castro F. .Hot isostatic pressing of ultrafine tungsten carbide-cobalt hardmetals[J].Journal of Materials Science,2002(19):4189-4195.
[18] Jianfei Sun;Faming Zhang;Jun Shen .Characterizations of ball-milled nanocrystalline WC-Co composite powders and subsequently rapid hot pressing sintered cermets[J].Materials Letters,2003(21):3140-3148.
[19] Seung I. Cha;Soon H. Hong;Byung K. Kim .Spark plasma sintering behavior of nanocrystalline WC-10Co cemented carbide powders[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2003(1/2):31-38.
[20] Zhao SX;Song XY;Zhang JX;Liu XM .Effects of scale combination and contact condition of raw powders on SPS sintered near-nanocrystalline WC-Co alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2008(1/2):323-329.
[21] McCandish L E;Kear B H;Kim B K .Carbothermic reaction process for making nanophase WC-Co powder[P].US:5230729,1993.
[22] Bernhard Wittmann;Wolf-Dieter Schubert;Benno Lux .WC grain growth and grain growth inhibition in nickel and iron binder hardmetals[J].International Journal of Refractory Metals & Hard Materials,2002(1):51-60.
[23] 徐庆荣,黎先财,杨沂凤,王燕.超细碳化钨的制备及其性能研究[J].稀有金属,2009(01):133-136.
[24] Sakangi R K;McCandish L E;Kear B H;Seegopaul P.Grain growth inhibition in liquid phase sintered nanophase WC/Co alloys[J].Advances in Powder Metallurgy and Particulate Materials,1998(01):51.
[25] Xu Wang;Zhigang Zak Fang;Hong Yong Sohn .Grain growth during the early stage of sintering of nanosized WC-Co powder[J].International Journal of Refractory Metals & Hard Materials,2008(3):232-241.
[26] 王洪涛,王旭,余永宁.纳米WC/Co硬质合金粉末烧结早期的晶粒长大研究[J].稀有金属与硬质合金,2005(01):18-21.
[27] Gille G;Szesny B;Dreyer K;van den Berg H Schmidt J Gestrich T Leitner G .Submicron and ultrafine grained hardmetals for micmdrills and metal cutting inserts[J].International Journal of Refractory Metals and Hard Materials,2002,20(01):3.
[28] Da Silva A G P;Schubert;Lux B .The role of the binder phase in the WC-Co sintering[J].Materials Research,2001,4(02):59.
[29] Carroll D F.Effect of cobalt size on the processing and properties of fine-grained WC/Co materials[A].Vancouver Canada:MPIF,1999:103.
[30] Mort P R;Riman R E .Determination of homogeneity scale in ordered and partially ordered mixtures[J].Powder Technology,1995,82(01):93.
[31] Oehlers M;Tybaert C;Peersman J;German R,Potter T,Yang M J.Comparison of different cobalt powders in cemented carbide grades[A].Annapolis,US:MPIF,2000:115.
[32] 汪中玮,张卫兵,何惧.钴粉形貌和粒度对低钴超细硬质合金性能的影响[J].粉末冶金工业,2008(01):14-18.
[33] Meissl C;Edtmaier C;Schubert W D;Schon A,Bock A,Zeiler B.A nevel route to ultrafine and nano-sized cobalt powders[A].,2005:339.
[34] 谭兴龙,易茂中,罗崇玲.球形钴粉的制备及其在超细晶粒硬质合金中的应用[J].中国有色金属学报,2008(02):209-214.
[35] 陈青林.我国钴粉的生产现状和技术进展[J].稀有金属与硬质合金,2001(03):34-38.
[36] 郑化桂;曾京辉;梁家和 .Fe,Co,Ni纳米粉化学还原制备机理的光谱研究[J].金属学报,1999,35(08):837.
[37] 高玉喜 .纳米WO<,3>制备技术优化及晶粒长大抑制剂添加技术的研究[D].北京科技大学,2007.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%