欢迎登录材料期刊网

材料期刊网

高级检索

在VGF法生长6英寸GaAs单晶的实际生长过程中,坩埚与坩埚托之间难以实现完全的理想贴合.坩埚与埚托之间的空隙对晶体生长过程中的温场和固液界面形状影响较大.通过模拟计算5种不同的空隙形状时的温场与热应力分布,发现随着空隙面积的增大,固液界面在轴向上的位置逐渐下降.在锥形空隙情况下,得到一个平坦的固液界面.设计了两种不同的空隙填充方案,模拟计算的结果表明,液态Ga完全填充时,在晶体轴向上热应力的分布较为平缓,有利于生长低位错、高质量的GaAs单晶.

参考文献

[1] Rudolph P.;Jurisch M. .Bulk growth of GaAs An overview[J].Journal of Crystal Growth,1999(Pt.1):325-335.
[2] Kuma S;Shibato M;Inada T.Gallium Arsenide and Related Compounds[M].Bristol:IOP,1994:497.
[3] Hashio K;Sawada S;Tatsumi M;Fujita K .Low dislocation density Si-doped GaAs single crystal grown by the vapor-pressure-controlled Czechralski method[J].Journal of Crystal Growth,1997,173(1-2):33.
[4] Rudolph P;Nuebert M;Arulkumaran S;Seifert M .Vapour pressure controllod Czochralski(VCZ)growth:a method to produce electronic materials with low dislocation density[J].Crystal Research and Technology,1997,32(01):35.
[5] Gault W A;Monberg E M;Clemans J E .A novel application of the vertical gradient freeze method to the growth of high quality Ⅲ-Ⅴ crystals[J].Journal of Crystal Growth,1986,74(03):491.
[6] Banos N;Friedrich J;Muller G .Simulation of dislocation density: Global modeling of bulk crystal growth by a quasi-steady approach of the Alexander-Haasen concept[J].Journal of Crystal Growth,2008(2):501-507.
[7] 丁国强,苏小平,屠海令,张峰燚
[8] Lukanina M A;Hodosevitch K V;Kalaev V V .3D numerical simulation of heat transfer during horizontal direct crystallization of corundum single crystals[J].Journal of Crystal Growth,2006,287:330.
[9] 涂凡,苏小平,屠海令,张峰燚,丁国强,王思爱.VGF法GaAs单晶位错分布的数值模拟和Raman光谱研究[J].稀有金属,2010(02):237-242.
[10] 涂凡,苏小平,张峰燚,黎建明,丁国强,王思爱.VGF法生长4英寸GaAs单晶固液界面形状和热应力的数值模拟研究[J].稀有金属,2011(03):388-393.
[11] Jordan A S .An evaluation of the thermal and elastic constants affecting GaAs crystal growth[J].Journal of Crystal Growth,1980,49:631.
[12] Tsai C T;Yao M W;Chait A .Prediction of dislocation generation during Bridgman growth of GaAs crystals[J].Journal of Crystal Growth,1992,125:69.
[13] Yonenaga I;Onose U;Sumino K .Mechanical properties of GaAs crystals[J].Journal of Materials Research,1987,2:252.
[14] Maroudas D;Brown R A .On the prediction of dislocation formation in semiconductor crystals grown from the melt:analysis of the Haasen model for plastic deformation dynamics[J].Journal of Crystal Growth,1991,108:399.
[15] Koai K;Sonnenberg K;Wenzl H .Influence of crucible support and radial heating on the interface shape during vertical Bridgman GaAs growth[J].Journal of Crystal Growth,1994,137(01):59.
[16] Muller G.;Birkmann B. .Optimization of VGF-growth of GaAs crystals by the aid of numerical modelling[J].Journal of Crystal Growth,2002(Pt.3):1745-1751.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%