过渡金属硼化物因其具有超硬特性而受到人们的关注,有望广泛应用于切屑加工工具、耐磨涂层、研磨材料等领域.介绍了制备过渡金属硼化物块体和薄膜材料的主要方法,并总结了部分过渡金属二元硼化物的结构和性能.不同过渡金属硼化物的结构不同,属于单斜、正交、六方等晶系；过渡金属硼化物薄膜材料的厚度在1μm以下；其硬度高于块体材料的硬度,达到超硬水平；但制得的过渡金属硼化物块体材料的硬度并不理想,与金刚石和立方氮化硼相比尚有一定的差距,还需进一步改进材料设计理念和探索新的制备方法.
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