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研究了稀土Y在亚共晶铝硅合金中诱发稀土-铝共晶反应对铝合金初生α相的细化效应;应用Bramfitt提出的方法,计算了Al-Y共晶反应产物Al3Y与α-Al界面的二维点阵错配度,结果显示两者的二维错配度<6%,即Al3Y可作为α-Al的异质形核质点,且能达到中等有效形核而起到细化晶粒的作用,并通过实验验证计算结果如下:选用稀土元素Y作为A356合金细化剂的同时,将A356-Y熔体分别在稀土钇-铝共晶温度上、下10℃左右保温t2 min后快速冷却,获得试样的金相组织照片后利用图像分析工具得到A356-Y合金初生α相的平均晶粒尺寸和平均形状因子.实验结果表明:A356-Y合金在Al-Y共晶温度之下保温,可获得较理想的初生α相形貌和较小的晶粒尺寸;结合二维错配的计算结果,可推断初生α相细化的主要原因为异质形核质点的增加:Al-Y共晶反应产物Al3Y与α-Al的二维点阵错配度在中等有效形核范围内,具有细化合金初生α相的作用;另一共晶产物α-Al与初生α相具有相同的晶体结构和点阵常数,则其也可作为异质形核质点而起到细化合金的作用.稀土Y可作为半固态A356合金中初生α相的优质细化剂.

参考文献

[1] Z. Fan .Semisolid metal processing[J].International Materials Reviews,2002(2):49-85.
[2] Bao Li;Hongwei Wang;Jinchuan Jie .Microstructure evolution and modification mechanism of the ytterbium modified Al-7.5%Si-0.45%Mg alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2011(7):3387-3392.
[3] Maja Voncina;Stanislav Kores;Primoz Mrvar .Effect of Ce on solidification and mechanical properties of A360 alloy[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2011(27):7349-7355.
[4] MEHDI HOSSEINIFAR;DMITRI V. MALAKHOV .The Sequence of Intermetallics Formation during the Solidification of an Al-Mg-Si Alloy Containing La[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,2011(3):825-833.
[5] 刘政,石凯,陈明.用低过热度浇注技术制备半固态ZL101-Sc铝合金[J].铸造,2009(07):662-665,670.
[6] 陈红梅,范常有,柳玉柱,文衍宣,钟夏平.Ce含量对Al在3.5%NaCl溶液中腐蚀行为影响的研究[J].稀有金属,2011(05):657-661.
[7] 唐小龙,彭继华,黄芳亮,许德英,杜日升.混合稀土含量对A356铝合金组织结构的影响[J].中国有色金属学报,2010(11):2112-2117.
[8] YUNTAO LI;ZHIYI LIU;QINGKUN XIA .Grain Refinement of the Al-Cu-Mg-Ag Alloy with Er and Sc Additions[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,2007(11):2853-2858.
[9] Cavaliere P .Effect of minor Sc and Zr addition on the mechanical properties of Friction Stir Processed 2024 aluminium alloy[J].Journal of Materials Science,2006(13):4299-4302.
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