The reaction enthalpy of solid-solid coordination reaction of L-Leucine with copper acetate is determined by solution calorimetry in an isoperibel reaction calorimeter. The calorimetric solvent is the solution of hydrochloric acid(4 mol/L), a new thermochemical cycle is designed. The values of △fHθm=1S. 64 kJ/mol, △fHθm(trans-Cu(L-Leu)2,s)=-1194. 7 kJ/mol are evalcated.
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