Six complexes of tetra(4-p-decanoyloxyphenyl)porphyrin(TDPPH2)with Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) and Zn (Ⅱ) have been synthesized in a mixed solvents of CH2Cl2 and DMF. The compounds were characterized by elemental analysis, UV-Vis, FTIR photoacoustic spectrometry, 1H NMR and molar conductance measurements. The optical textures of the isotropic liquid crystals of TDPPH2 and TDPPZn on cooling were observed by polarized light microscope.
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