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将碳纳米管部分掺入石墨材料中用作锂离子电池电极材料,二者形成许多纳米级微孔,为锂离子提供了更多的嵌入脱出空间,使可逆容量得以提高,而且碳纳米管可以起到桥梁的作用,增强了材料的导电性,避免了石墨在充放电过程中产生孤岛效应.结果表明,这种掺杂材料的首次可逆容量为341.8 mA·h/g,循环10次后可逆容量保持率为94.5%.

Carbon nanotubes and graphite were mixed and used as anode material for lithium ion bat-tery. A great many of nano-scale pores were formed between carbon nanotubes and graphite, improv-ing the charge-discharge capacity of the mixture. Moreover,as a bridge, the carbon nanotubes couldimprove the property of electric conduction and avoid the effect of isolated island during the lithium in-tercalation and e-intercalation. The reversible capacity of the anode materials on first cycle was341.8 mA· h/g, and maintained at 94.5% after 10 cycles. The charge-discharge behavior of themixed materials was better than that of the single carbon nanotubes or graphite.

参考文献

[1] Ijima S. Nature,1991,354:56
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[5] Dahn J R,Zhang T,Xue J S, et al. Sciences,1995,270:590
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