综述了近年来直接甲醇燃料电池(DMFC)中阴极催化剂研究进展. 目前DMFC中所用的阴极催化剂一般是Pt,其主要问题是对氧还原的电催化活性低及透过隔膜的甲醇燃料会使阴极催化剂的性能降低. 在Pt催化剂中添加如Cr、Ni、杂多酸或过渡金属的卟啉和酞菁化合物等,不但能提高Pt对氧还原的电催化活性,而且还能较大幅度地提高Pt的耐甲醇能力,因此,这些Pt基复合催化剂有望用作为DMFC的阴极催化剂.
参考文献
| [1] | Hogarth M P,Hards G A. Platinum Metals Rev[J],1996,40:150 |
| [2] | Lamy C,Lima A. J Power Sources[J],2002,105:283 |
| [3] | Yang H,Alonso-Vante N,Leger J M, et al. J Phys Chem B[J],2004,108:1 938 |
| [4] | Ralph T R,Hongarth M P. Platinum Metals Rev[J],2002,46:3 |
| [5] | Kinoshita K. J Electrochem Soc[J],1990,137:845 |
| [6] | Maillard F,Martin M,Gloguen F. Electrochim Acta[J],2002,47:3 431 |
| [7] | TANG Ya-Wen(唐亚文),LI Gang(李钢),YANG Hui(杨辉), et al. J. Nanjing Normal Univ(南京师范大学学报)[J],2003,26:112 |
| [8] | Landsman D A,Luczak F J. US 4 316 944[P],1982 |
| [9] | Jalan V M,Taylor E J. J Electrochem Soc[J],1984,84:546 |
| [10] | Landsman C A,Luczak F J. US 4 316 944[P],1980 |
| [11] | Luzak F J,Landsman D A. US 4 447 506[P],1983 |
| [12] | Mukerjee S,Srinivasan S. J Electroanal Chem[J],1993,357:201 |
| [13] | Drillet J F,Ee A,Friedemann J. Electrochim Acta[J],2002,47:1 983 |
| [14] | Xiong L,Kannan A M,Manthiram A. Electrochim Acta[J],2004,49:4 163 |
| [15] | LU Yan-Zhuo(吕艳卓). Doctoral Dissertation([博士学位论文]). Changchun(长春):Changchun Institute of Applied Chemistry,Cinese Academy of Sciences(中国科学院长春应用化学研究所),2005 |
| [16] | Jasinski R. Nature[J],1964,201:1 212 |
| [17] | Wiesener K,Ohms D,Neumann V, et al. Mater Chem Phys[J],1989,22:457 |
| [18] | Jahnke H,Schnborn M,Zimmermann G. Top Curr Chem[J],1976,61:133 |
| [19] | Bagotzky V S,Tarasevich M R,Radyushkina K A, et al. J Power Sources[J],1997,2:233 |
| [20] | Bouwkamp-Wijnoltz A L,Visscher W,Van Veen J A R, et al. Electrochim Acta[J],1999,45:379 |
| [21] | Lefevre M,Dodelet J P,Bertrand P. J Phys Chem B[J],2000,104:1 123 810 |
| [22] | Coutanceau C,Ei H A,Crouigneau P, et al. Electrochim Acta[J],1995,40:2 739 |
| [23] | Deryn C,Jiang R Z,Chu D. Solid State Ionics[J],2002,148:591 |
| [24] | Jiang J H,Kucernak A. Electrochim Acta[J],2002,47:1 967 |
| [25] | Jiang R Z,Chu D Y. J Electrochem Soc[J],2000,147:4 605 |
| [26] | LI Xu-Guang(李旭光),XING Wei(邢巍),LU Tian-Hong(陆天虹). Chem J Chin Univ(高等学校化学学报)[J],2003,24:1 246 |
| [27] | Alonso-Vante N,Tributsch H. Nature[J],1986,323:431 |
| [28] | Schmidt T J,Paulus U A,Gasteiger H A. J Electrochem Soc[J],2000,147:2 620 |
| [29] | Trapp V,Christensen P A,Hamnett A. J Chem Soc Faraday Trans[J],1996,92:4 311 |
| [30] | Reeve R W,Christensen P A,Dickinson A J, et al. Electrochim Acta[J],2000,45:4 237 |
| [31] | Solorza-Feria O,Citalan-Cigarroa S,Rivera-Noriega R. Electrochem Comm[J],1999,1:585 |
| [32] | Pattabi M,Castellanos R H,Sebastian P J. Electrochem Solid-State Lett[J],2000,3:431 |
| [33] | Sebastian P J. Int J Hydrogen Energy[J],2000,25:255 |
| [34] | Rodriguez F J,Sebastian P J. Int J Hydrogen Energy[J],2000,25:243 |
| [35] | Rhun V L,Garnier E,Pronier S, et al. Electrochem Comm[J],2000,2:475 |
| [36] | Cere′ S,Vazquez M,de Sa′nchez S R, et al. J Electroanal Chem[J],2001,505:118 |
| [37] | Wei Z D,Huang W Z. J Power Sources[J],2000,91:83 |
| [38] | Manoharan R,Goodenough J B. Electrochim Acta[J],1995,40:303 |
| [39] | Prakash J,Tryk D A,Yeagerc E B. J Electrochem Soc[J],1999,146:4 145 |
| [40] | TANG Zhi-Yuan(唐致远),SONG Shi-Dong(宋世栋),LIU Jian-Hua(刘建华). Battery Tech(电源技术)[J],2003,27:233 |
| [41] | Heller-Ling N,Prestat M,Gautier J L, et al. Electrochim Acta[J],1997,42:197 |
| [42] | Cong H N,Abbassi K E,Chartier P. Electrochem Solid-State Lett[J],2000,3:192 |
| [43] | Hayashi M,Uemura H,Shimanoe K. Electrochem Solid-State Lett[J],1998,1:268 |
| [44] | Suresh K,Panchapagesan T S,Patil K C. Solid State Ionics[J],1999,126:299 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%