合成了取代型多金属氧酸盐与HCl共掺杂聚苯胺HCl-SiW11Co/PAn材料,测试了其热稳定性、荧光性质、导电性、电化学性质及磁学性质等功能特性. 实验结果表明,合成的掺杂态聚苯胺新材料HCl-SiW11Co/PAn比本征态聚苯胺(PAn)的热分解温度提高162 ℃;具有荧光性质和较强的导电能力,室温电导率σ=0.54 S/cm. 合成的新材料体系呈顺磁性,磁化强度相对于多金属氧酸盐SiW11Co显著增强. 合成的新材料为电化学活性材料.
参考文献
| [1] | Chiang C K,Druy M A,Gan S C,et al.J Amer Chem Soc[J],1978,100:1 013 |
| [2] | Bernier P,Lefrant S,Bidan G,Ed.Advances in Synthetic Metals.Twenty Years of Progress in Science and Technology[M].Netherlands:Elsevier Science Press,1999:103～112,367～383,349～363 |
| [3] | WANG En-Bo(王恩波),HU Chang-Wen(胡长文),XU Lin(许林).Introduction on Polyacid Chemistry(多酸化学导论)[M].Beijing(北京):Chemical Industry Press(化学工业出版社),1998 |
| [4] | Hasik M,Turek W,Stochmal E,et al.J Catal[J],1994,147:544 |
| [5] | Qu L-Y,Lü R-Q,Peng J,et al.Synth Met[J],1997,84:135 |
| [6] | Gong J,Su Z-M,Wang R-S,et al.Synth Met[J],1999,101:750 |
| [7] | Lira-Cantis M,Gomez-Romero P.Chem Mater[J],1998,10:698 |
| [8] | Gong J,Cui X-J,Xie Z-W,et al.Synth Met[J],2002,129:187 |
| [9] | Weakley T J R,Malik S A.J Inorg Nucl Chem[J],1967,29:2 935 |
| [10] | Hwang G W,Wu K Y,Hua M Y,et al.Synth Met[J],1998,92:39 |
| [11] | Gong J,Hua R-N,Xie Z-W,et al.Polym J[J],2001,33:377 |
| [12] | Pron A.Synth Met[J],1992,46:277 |
| [13] | MacDiamid A G,Epstein A J.Synth Met[J],1994,65:103 |
| [14] | Somani P R,Marimuthu R,Mandale A B.Polymer[J],2001,42:2 991 |
| [15] | He C,Tan Y W,Li Y F.J Appl Polym Sci[J],2003,87:1 537 |
| [16] | Epstein A J,Ginger J M,Richter A F,et al..In Conducting Polymer,Special Applications[M].Alcacer X L Ed.Dordrecht,Holland:D Reidel Publishing Company,1987:121 |
| [17] | JIAO Jian(焦剑),LEI Wei-Yuan(雷渭媛).Structure,Properties and Measurements of Polymers(高聚物结构、性能和测试)[M].Beijing(北京):Chemistry Industry Press(化学工业出版社),2003:633 |
| [18] | Gong J,Cui X-J,Wang R-S,et al.Synth Met[J],2002,129:15 |
| [19] | Gong J,Yu J-Z,Chen Y-G,et al.Mater Lett[J],2002,57:765 |
| [20] | Aprano G D,Lecleric M,Zotti G.Macromole[J],1992,25:2 145 |
| [21] | Lapkowski M,Berrada K,Quillard S.Macromole[J],1995,28:1 233 |
| [22] | ZHANG Bao-Jian(张保建),QU Lun-Yu(瞿伦玉),LIU Jing-Fu(刘景福),et al.Chem Acta(化学学报)[J],1987,45:232 |
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