采用DSC和红外测试技术研究了环氧树脂与1,8-间萘二胺的固化过程.结果表明,反应的理论凝胶温度Ti为360.33K、固化温度Tp为391.79K、后固化温度Tf为413.05K;并由Kissinger和Ozawa方法分别求得固化反应的表观活化能ΔE为67.166和70.379kJ/mol,依据Crane理论得到固化反应级数为n=1.00.
参考文献
| [1] | CHEN Ping(陈平),LIU Sheng-Ping(刘胜平).Epoxy Resin(环氧树脂)[M].Beijing(北京):Chemical Industry Perss(化学工业出版社),1999,3:1 |
| [2] | Kissinger H E.J Res Nat Stand[J],1956,57:217 |
| [3] | Crane L W.J Polym Sci Polym Lett Edn[J],1973,(11):533 |
| [4] | Ozawa T Y.J Thermal Anal[J],1970,2:301 |
| [5] | ZHANG Xiang-Yu(张向宇).Analysis and Testing Technology of Adhesive(胶黏剂分析与测试技术)[M].Beijing(北京):Chemical Industry Perss(化学工业出版社),2004,5:250 |
| [6] | HU Yu-Ming(胡玉明),WU Liang-Yi(吴良义).Curing Agent(固化剂)[M].Beijing(北京):Chemical Industry Perss(化学工业出版社),2004,2(9):18 |
| [7] | XUAN Yi-Ning(宣宜宁),LIU Wei-Qu(刘伟区),LI Yan(黎艳).China Synthetic Resin and Plastics(合成树脂及塑料)[J],2004,21(5):35 |
| [8] | Shokrolahil F,Sadiand M,Shokrolahil P.Thermal Anal and Calorimetry[J],2005,(82):151 |
| [9] | ZHU Huai-Wu(朱淮武).Spectrum Analysis of the Organic Molecule Structure(有机分子结构波谱解析)[M].Beijing(北京):Chemical Industry Perss(化学工业出版社),2005(9):251 |
| [10] | Macan J,Brnardi I,Ivankovi M,Mencer H J.Thermal Anal and Calorimetry[J],2005,(81):369 |
| [11] | Ramirez C,Abad M J,Barral L,Cano J,Diez F J,Lopez J,Montes R,Polo J.Thermal Anal and Calorimetry[J],2003,(72):421 |
| [12] | WANG De-Sheng(王德生),CHEN Wei(陈维),LIU Bin(刘斌),CHEN Shou-Tian(陈寿田).J Xi'an Jiaotong Univ(西安交通大学学报)[J],2000,34(5):1 |
| [13] | Acitelli M A,Prime R B,Sacher E.Polymer[J],1971,12:335 |
| [14] | Dave R S,Loos A C,Auths(著).FANG Zheng-Ping(方郑平)Tram(译).Macromolecule Compound Material Process Engineering(高分子复合材料加工工程)[M].Beijing(北京):Chemical Industry Perss(化学工业出版社),2004,1:56 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%