设计制备了一种新的常温自旋交叉配合物[Fe(dpp)(Mepy)2(NCS)2]. 通过元素分析、红外光谱、电喷雾质谱和紫外光谱等测试技术对该配合物进行了结构表征. 变温磁化率研究发现,该配合物的自旋转换温度Tc=330 K. 通过与同体系其它配合物的比较发现,配体的修饰对自旋交叉临界温度以及回滞宽度均有显著影响.
参考文献
| [1] | Real J A,Gaspar A B,Niel V,Muňoz M C.Coord Chem Rev[J],2003,236:121 |
| [2] | Kahn O,Martinez C J.Science[J],1998,279:44 |
| [3] | Létard J F,Guionneau P,Codjovi E,Lavastre O,Bravic G,Chasseau D,Kahn O.J Am Chem Soc[J],1997,119:10 861 |
| [4] | Reger D L,Gardinier J R,Elgin J D,Smith M D.Inorg Chem[J],2006,45:8 862 |
| [5] | Zhong Z J,Tao J Q,Yu Z,Dun C Y,Liu Y J,You X Z.J Chem Soc Dalton Trans[J],1998:327 |
| [6] | Yu Z,Liu K,Tao J Q,Zhong Z J,You X Z,Siu G G.Appl Phys Lett[J],1999,74:4 029 |
| [7] | Spacu P,Teodorescu M,Filotti G,Telnic P Z.Anorg Allg Chem[J],1972,392:88 |
| [8] | Claude R,Real J A,Zarembowitch J,Kahn O,Ouahab L,Grandjean D,Boukheddaden K,Varret F,Dworkin A.Inorg Chem[J],1990,29:4 442 |
| [9] | Tao J Q,Gu Z G,Wang T W,Yang Q F,Zuo J L,You X Z.Inorg Chim Acta[J],2007,360:4 125 |
| [10] | TAO Jian-Qing(陶建清),YU Zhi(余智),You Xiao-Zeng(游效曾).Acta Chim Sin(化学学报)[J],2004,62:489 |
| [11] | Erickson N E,Sutin N.Inorg Chem[J],1966,5:1 834 |
| [12] | Zhu D R,Xu Y,Yu Z,Guo Z J,Sang H,Liu T,You X Z.Chem Mater[J],2002,14:838 |
| [13] | Kahn O,Kr(O)eber J,Jay C.Adv Mater[J],1992,4:718 |
| [14] | YIN Fu-Ling(尹富玲),SHEN Jia(申佳),ZOU Jia-Jia(邹佳嘉),LI Rong-Chang(李荣昌).Acta Chim Sin(化学学报)[J],2003,61:556 |
| [15] | TAO Jian-Qing(陶建清),SHI Wei-Zhong(施卫忠),ZHUAN Xiao(庄晓),YU Zhi(余智),YOU Xiao-Zeng(游效曾).Chinese J Inorg Chem(无机化学学报)[J],2002,18:255 |
| [16] | TAO Jian-Qing(陶建清),YU Zhi(余智),SHAO Ting(邵挺),DAI Yao-Dong(戴耀东),CHEN Xue-Tai(陈学太).Chinese J Inorg Chem(无机化学学报)[J],2002,18:582 |
| [17] | TAO Jian-Qing(陶建清),YU Zhi(余智),SHAO Ting(邵挺),WANG Tian-Wei(王天维),YOU Xiao-Zeng(游效曾).Chinese J Appl Chem(应用化学)[J],2003,20:1 102 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%