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采用水解-均相沉淀法在常温下制得纯锐钛矿型的纳米TiO2粉末,对所制得的粉末进行了TEM、XRD、EDS、XPS和UV-VIS分析.结果表明:通过添加NH4Cl和H2SO4可在室温下制得粒径为32nm的纯锐钛矿型纳米TiO2粉末,并且粉末粒径均匀,尺寸分布较窄;纳米TiO2粉末对波长200~360 nm范围内的紫外线有较好的吸收作用,且吸收较均匀.

参考文献

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[2] Hengerer R.;Erbudak M.;Gratzel M.;Bolliger B. .Structure and stability of the anatase TiO2 (101) and (001) surfaces[J].Surface Science: A Journal Devoted to the Physics and Chemistry of Interfaces,2000(1/3):162-169.
[3] Yoshiyuki Sakai;Shaw Ehara .Scanning tunneling microscopy/spectroscopy study of point defects on TiO2 (110)- (1 × 1)surface[J].Japanese Journal of Applied Physics,2001,40:773-775.
[4] Ravirajan P;Haque S A;Durrant J R et al.Hybrid nanocrystalline TiO2 solar cells with a fluorence-thiophene copolymer as a sensitizer and hole conductor[J].Journal of Applied Physics,2003,95(03):1473-1480.
[5] Ruan Shengping;Wu fengqing;Zhang Tong et al.Surface state studies of TiO2 nanoparticles and photocatalytic degradation of methyl orange in aqueous TiO2 disperisious[J].Materials Chemistry and Physics,2001,69:7-9.
[6] Arbiol J;Cerda J;Dezanneau G et al.Effects of Nb doping on the TiO2 natase-to-rutile phase transition[J].Journal of Applied Physics,2002,92(02):853-861.
[7] On crystallite size dependence of phase stability of nanocrystalline TiO_(2)[J].Journal of Applied Physics,2003(7):4577-4582.
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