浮选技术适于从稀水溶液中富集痕量金属离子,且可用光谱分析法直接分析.本文综述了1996～2007年浮选技术在金属分离/富集及分析中应用研究进展,对浮选的分类(离子浮选、沉淀浮选、溶剂浮选)和机理做以简单的概述,介绍了捕集剂浓度、溶液pH值、离子强度、气体流速等因素对浮选效率的影响,从捕集剂选择、pH值、浮选剂或表面活性剂的选择及回收率等方面对浮选技术在金属分离/富集及分析中的应用进行总结,并指出浮选技术存在的问题和发展方向.
参考文献
| [1] | Sheng-Yi Lee;Y Pang Tsui .Succeed at gas/liquid contacting[J].Chemical Engineering Progress,1999,7:23-49. |
| [2] | John T H;Donald M;Robert G et al.Partitioning of organic chemicals at the air-water interface in environmental systems[J].Environmental Science and Technology,1993,27(10):2174-2180. |
| [3] | Luuk K K;顾惕人.浮选物理化学原理的某些进展[J].化学通报(印刷版),1995(10):16-24. |
| [4] | Sebba F.Solvent Sublation,Ion Floation[M].New York:American Elsevier,1962:112-117. |
| [5] | Thoma G J;Bowen M L;Hollensworth D.Dissolved air precipitation/solvent sublation for oil-field produced water treatment[J].Separation and Purification Technology,1999(16):101-107. |
| [6] | B.Glenn Bryson;Kalliat T.Valsaraj .Solvent sublation for waste minimization in a process water stream - a pilot-scale study[J].Journal of hazardous materials,2001(1):65-75. |
| [7] | Lu YJ;Liu HJ;Tang J;Wei B;Zhang XL .The removal of humic acids from water by solvent sublation[J].Journal of Colloid and Interface Science,2005(1):278-284. |
| [8] | Grattoni C A;Dawe R A .Gas and oil production from water flood residual oil:effect of wettability and oil spreading characteristics[J].Journal of Petroleum Science and Engineering,2003,39:297-308. |
| [9] | Thoma G J;Bowen M L;Hollensworth D .Dissolved air precipitation/solvent sublation foroil-field produced water treatment[J].Separation and Purification Technology,1999,16:101-107. |
| [10] | 吕玉娟,朱锡海.溶剂气浮分离技术研究现状与发展方向[J].化学进展,2001(06):441-449. |
| [11] | Tharapiwattananon N.;Osuwan S.;Harwell JH.;Haller KJ.;Scamehorn JF. .SURFACTANT RECOVERY FROM WATER USING FOAM FRACTIONATION[J].Separation Science and Technology,1996(9):1233-1258. |
| [12] | Shen H T;Forssherg E;Pugh R J .An example of innovation from the waste management industry:Deinking flotation cells[J].Res Con Rec,2001,33(01):37-39. |
| [13] | Finch J A;Hardie C .An example of innovation from the waste management industry:deinking flotation cells[J].Mining Engineering,1999,12(05):467-475. |
| [14] | J. Rubio;M.L. Souza;R.W. Smith .Overview of flotation as a wastewater treatment technique[J].Minerals Engineering,2002(3):139-155. |
| [15] | 周春山.化学分离富集方法及应用[M].长沙:中南工业大学出版社,2001 |
| [16] | 张文清.分离分析化学[M].上海:华东理工大学出版社,2007 |
| [17] | Karger B L.Adsorptive bubble separation techniques[M].New York:Academic Press,Inc,1972:578-591. |
| [18] | 徐其亨.浮选分离及其在分析化学中的应用[J].化学通报(印刷版),1981(11):42-47. |
| [19] | 董慧茹;乐秀毓.溶剂浮选吸光度法的理论与实践[J].化学通报(印刷版),1987(02):1-7. |
| [20] | Valsaraj K T;Thibodeaux L J .Studies in batch and continuous solvent sublation Ⅱ.Continuous countercurrent solvent sublation of neutral and ionic species from aqueous solutions[J].Separation Science and Technology,1991,26(03):367-380. |
| [21] | Yujuan Lu;Xihai Zhu .A mathematical model and mechanism of sublation of dye-surfactant ion complexes[J].Analytical and bioanalytical chemistry,2002(5):906-914. |
| [22] | Y.-J. Lu;X.-H. Zhu .A mathematical model of solvent sublation of some surfactants[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2002(5):891-898. |
| [23] | Lu YJ.;Liu JH.;Xiong Y.;Zhu XH. .Study of a mathematical model of metal ion complexes in solvent sublation[J].Journal of Colloid and Interface Science,2003(1):261-269. |
| [24] | 闫永胜,黄卫红,陆晓华.碘-溴化十六烷基三甲铵缔合体系溶剂浮选褪色光度法测定SO32-的研究[J].分析试验室,2004(04):25-27. |
| [25] | Yoshiyuki O.Foam separation processes[A].,2001:173-184. |
| [26] | Lee;Maa J J R .Separation of a surface active solute by foam fraction[J].International Journal Heat Mass and Transfer,1988,13t:465-473. |
| [27] | Bhattacharya;Ghosal P;Sen S K .Column design parameters for foam fractionation human placental extract[J].Separation Science and Technology,1994,29(07):855-865. |
| [28] | 曾文炉,李浩然,李宝华,丛威,蔡昭铃,欧阳藩.螺旋藻泡载分离法采收的实验室研究[J].过程工程学报,2002(01):40-44. |
| [29] | 胡熙庚;黄和慰;毛钜凡.浮选理论与工艺[M].长沙:中南工业大学出版社,1991 |
| [30] | A·A·阿布拉莫夫.浮选理论及浮选问题解决方法[J].国外金属矿选矿,2002(03):16-20. |
| [31] | Wolffs P;Norling B;Radstrom P .Risk assessment of false-positive quantitative real-time PCR results in food, due to detection of DNA originating from dead cells[J].Journal of Microbiological Methods,2005(3):315-323. |
| [32] | Colin F. Poole .New trends in solid-phase extraction[J].TrAC: Trends in Analytical Chemistry,2003(6):362-373. |
| [33] | N. Fontanals;R.M. Marce;F. Borrull .New hydrophilic materials for solid-phase extraction[J].TrAC: Trends in Analytical Chemistry,2005(5):394-406. |
| [34] | Carvalho R N J;Moura L S;Paulo T V R et al.Supercritical fluid extraction from rosemary (rosmarinusofficipalis):kinetic data,extract's global yield,composition,and antioxidant activity[J].Journal of Supercritical Fluids,2005,35:197-204. |
| [35] | Moura LS;Carvalho RN;Stefanini MB;Ming LC;Meireles MAA .Supercritical fluid extraction from fennel (Foeniculum vulgare): global yield, composition and kinetic data[J].The Journal of Supercritical Fluids,2005(3):212-219. |
| [36] | Perakis C;Louli V;Magoulas K .Supereritical fluid extraction of black pepper oil[J].Journal of Food Engineering,2005,71(04):386-393. |
| [37] | 刘勇建,牟世芬,杜兵,林爱武.微波浓缩-离子色谱法测定饮用水中的痕量溴酸根和高氯酸根[J].色谱,2002(02):129-132. |
| [38] | 袁东,但德忠,罗方若.微波消解在环境分析中的应用及进展[J].现代科学仪器,2000(03):42-44,47. |
| [39] | Jun Ya;Rajinder Pal .Osmotic swelling behavior of globules of W/O/W emulsion liquid membranes[J].Journal of Membrane Science,2001(1):79-91. |
| [40] | Yan J;Pal R .Effects of aqueous-phase acidity and salinity on isotonic swelling of W/O/W emulsion liquid membranes under agitation conditions[J].Journal of Membrane Science,2004(1/2):193-203. |
| [41] | Nohara P;Douglas V;Heitkemper T et al.Arsenic extraction and speciation in carrots using accelerated solvent extraction,liquid chromatography and plasma mass spectrum[J].The Analyst,2001,126:1011-1017. |
| [42] | Wenrich L;Popp P;Koller G et al.Determination of organo chlorine pesticides and chlorobenzenes in strawberries by using ASE combined with sportive enrichment and gas chromatography/mass spectrometry[J].Journal of Association of Official Analytical Chemists,2001,84:1194-1201. |
| [43] | Hubert A;Wenzel K .ASE more efficient extraction of POPs and PAHs from real contaminated plant and soils[J].Analytical Chemistry,2001,67:101-143. |
| [44] | 董慧茹,程群.溶剂浮选-石墨炉原子吸收光谱法测定水样中痕量Pb（Ⅱ）、Ni（Ⅱ）和Co（Ⅱ）[J].分析科学学报,2006(02):173-175. |
| [45] | 闫永胜,李春香,刘燕,王赟,包科技,陆晓华.苯溶剂浮选分光光度法测定工业废水中Cr（Ⅵ）的研究[J].冶金分析,2004(05):23-25. |
| [46] | 刘嘉敏;汪惊奇;张敏 .溶剂浮选吸光光度法测定痕量砷[J].理化检验-化学分册,1999,35(09):428,434. |
| [47] | 吴利欢,赵建芬,王洪英.浮选分离法的研究Ⅺ：钒的沉淀浮选富集--溶剂浮选分离分光光度法的研究与应用[J].西江大学学报,2000(02):61-65,78. |
| [48] | Young-Sang Kim;Je-Hyuk Shin;Yoon-seok Choi;Won Lee;Yong-Ill Lee .Solvent sublation using 8-hydroxyquinoline as a ligand for determination of trace elements in wate rsamples[J].Microchemical Journal: Devoted to the Application of Microtechniques in all Branches of Science,2001(2/3):99-107. |
| [49] | Qun Cheng;Huiru Dong .Solvent Sublation Using Dithizone as a Ligand for Determination of Trace Elements in Water Samples[J].Mikrochimica Acta: An International Journal for Physical and Chemical Methods of Analysis,2005(1):59-65. |
| [50] | Lu YJ.;Liu JH.;Xiong Y.;Zhu XH. .Study of a mathematical model of metal ion complexes in solvent sublation[J].Journal of Colloid and Interface Science,2003(1):261-269. |
| [51] | 陈婷玉,李春香,闫永胜.碘化钾-亚甲基蓝浮选光度法测定痕量Pb（Ⅱ）的研究[J].化学试剂,2006(08):485-486,504. |
| [52] | 闫永胜,徐婉珍,贾立群,王赟,陈婷玉.甲苯浮选2-巯基-β-萘并噻唑分光光度法测定钯[J].冶金分析,2006(03):77-78. |
| [53] | 李春香,徐婉珍,李松田,闫永胜.甲苯浮选金属离子-碘离子-甲基蓝缔合物光度法测定高盐溶液中痕量铜银镉锌[J].冶金分析,2007(03):75-77. |
| [54] | 闫永胜,秦永超,陆晓华.溶剂浮选三元缔合物光度法测定痕量锰的研究[J].分析科学学报,2003(01):48-50. |
| [55] | 王淑兰,陈淑桂,王多禧,王英华,王洪艳.溶剂浮选-偏最小二乘回归光度法测定地质样品中痕量贵金属元素[J].分析化学,1999(01):38-40. |
| [56] | 邓景黎,邓吉胜.溶剂浮选光度法测定水中镍[J].化工技术与开发,2003(04):31-33. |
| [57] | 王宗廷,董晓芳,金军昌.沉淀浮选吸光光度法测定钒[J].石油大学学报（自然科学版）,1999(05):113-114. |
| [58] | 周源,梁华银.分步沉淀浮选分离法处理矿山酸性废水试验研究[J].南方冶金学院学报,2004(01):67-69. |
| [59] | A·B·佐乌波乌里斯.从水溶液中浮选钴离子[J].国外金属矿选矿,2003(06):37-38,21. |
| [60] | 裴健,董红星,李占双,侯秀勤.气浮法去除水中铅离子的实验研究[J].应用科技,2004(12):63-65. |
| [61] | 陶有胜,朱联锡,张克仁.镍离子和铜离子沉淀浮选试验研究[J].水处理技术,1997(03):175. |
| [62] | 董红星,孙兆申,裴建,谷水波.铁盐共沉淀泡沫分离法去除水中铬离子[J].化工学报,2006(09):2116-2122. |
| [63] | 李琳;黄淦泉;冯易君 .二苯碳酰二肼离子浮选石墨炉原子吸收光谱测水中痕量铬(Ⅵ)与铬(Ⅲ)[J].四川大学学报(自然科学版),1997,34(04):469-473. |
| [64] | 董慧茹,张敬畅,胡少成.离子浮选分光光度法测定乙醛催化剂中的钯含量[J].光谱学与光谱分析,2004(03):345-347. |
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