基于Ni(Ⅱ)能置换出Cu(Ⅱ)-EDTA络合物中的Cu(Ⅱ),与鲁米诺-H2 O2-Cu(Ⅱ)化学发光体系相偶合,建立了测定Ni(Ⅱ)的置换偶合反应流动注射化学发光法测定Ni(Ⅱ)的新方法.考察了Cu(Ⅱ)-EDTA络合比、反应介质与pH、氧化剂的选择及其浓度以及鲁米诺浓度对体系相对发光强度的影响,并采用酒石酸掩蔽剂消除了干扰组分对测定的影响.在最佳的实验条件下,该方法测定Ni(Ⅱ)的线性范围为5.0×10-8～5.0×10-6 g/mL,检出限为2.0×10-8 g/mL(3σ).对环境水样中的镍(Ⅱ)进行测定,其结果同原子吸收光谱法的测定值相一致,相对标准偏差为3.7％～4.6％.
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