利用化学键的观点定量地研究了一些具有各种晶体结构实用材料的介电性质.采用已建立的化学键方法,分析了这些晶体的介电性质与其组成化学键之间的关系.更进一步,基于晶体的化学键方法提出了一个组合方法用于定量确定具有相似晶体结构材料的介电性质.从目前的工作中可以推导出光学晶体非线性起源的结构信息,因此可以在一定程度上帮助人们开展非线性光学晶体工程的研究工作.
From the chemical bond viewpoint, dielectric properties of some practical materials with various crystal structures were quantitatively studied. The correlation between constituent chemical bonds and dielectric properties of these crystals was analyzed using the proposed chemical bond method. Furthermore, on the basis of the chemical bond method a combination method was presented for the quantitative determination of dielectric properties of materials with a similar crystal structure. From the current work, we may derive structural information concerning the nonlinearity origin of optical crystals, which is helpful for the nonlinear optical crystal engineering.
参考文献
| [1] | Champagne B;Bishop D M .Calculations of Nonlinear Optical Properties for the Solid State[J].Advances in Chemical Physics,2003,126:41-92. |
| [2] | Xue D.;Hesse H.;Betzler K. .Dielectric properties of I-III-VI2-type chalcopyrite semiconductors[J].Physical Review.B.Condensed Matter,2000(20):13546-13551. |
| [3] | Xue D.;Hesse H.;Betzler K. .Dielectric constants of binary rare-earth compounds[J].Journal of Physics. Condensed Matter,2000(13):3113-3118. |
| [4] | Xue D.;Betzler K.;Hesse H.;Lammers D. .Linear and nonlinear optical susceptibilities of orthorhombic rare earth molybdates RE2(MoO4)(3)[J].The journal of physics and chemistry of solids,2002(2):359-361. |
| [5] | Phillips J C .Ionicity of the Chemical Bond in Crystals[J].Reviews of Modern Physics,1970,42:317-356. |
| [6] | Van Vechten J A .Quantum Dielectric Theory of Electronegativity in Covalent Systems. I. Electronic Dielectric Constant[J].Physical Review,1969,182:891-905. |
| [7] | Levine B F .Bond Susceptibilities and Ionicities in Complex Crystal Structures[J].Journal of Chemical Physics,1973,59:1463-1486. |
| [8] | Brown I D .Chemical and Steric Constraints in Inorganic Solids[J].ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE,1992,48:553-572. |
| [9] | Dongfeng Xue;Siyuan Zhang .Bond-charge calculation of nonlinear optical susceptibilities of LiXO_3 type complex crystals[J].Chemical Physics: A Journal Devoted to Experimental and Theoretical Research Involving Problems of Both a Chemical and Physical Nature,1998(3):307-318. |
| [10] | Dongfeng Xue;Siyuan Zhang .Chemical bond analysis of the correlation between crystal structure and nonlinear optical properties of complex crystals[J].Physica, B. Condensed Matter,1999(1/2):78-83. |
| [11] | Dongfeng Xue;Siyuan Zhang .The origin of nonlinearity in KTiOPO↓(4)[J].Applied physics letters,1997(5/8):943-945. |
| [12] | Xue DF.;Zhang SY. .NONLINEARITY OF THE COMPLEX CRYSTALS WITH O-H BOND[J].The journal of physics and chemistry of solids,1996(9):1321-1328. |
| [13] | Xue D;Ratajczak H .Predicting Optical Properties of Potassium Hydrogen bis-trichloroacetate Crystal[J].Bulletin of the Polish Academy of Sciences-Chemistry,2003,51:71-75. |
| [14] | Dongfeng Xue;Siyuan Zhang .Effect of hydrogen bonds on optical nonlinearities of inorganic crystals[J].Chemical Physics Letters,1999(5/6):449-452. |
| [15] | Baran J;Lis T;Marchewka M;Ratajczak H .Structure and Polarized IR and Raman-spectra of Na2SeO4·H2SeO3·H2O Crystal[J].Journal of Molecular Structure,1991,250:13-45. |
| [16] | Markworth A;Paulus H;Weiden N;Weiss A .CL-35 Zeeman Nuclear-quadrupole Resonance Spectroscopy and Crystal-structures of Trichloroacetates MH(Cl3CCOO)2, M = K, Rb[J].Zeitschrift für Physikalische Chemie,1991,173:1-19. |
| [17] | Xue D.;Hesse H.;Betzler K. .Dielectric properties of lithium niobate-tantalate crystals[J].Solid State Communications,2000(11):581-585. |
| [18] | Xue D;Betzler K;Hesse H;Lammers D .Relationship between Dielectric Responses and Constituent Atoms in Crystal Materials[J].Physica Status Solidi B,1999,216:R7-8. |
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