欢迎登录材料期刊网

材料期刊网

高级检索

本文主要研究了用VHF-PECVD方法制备的不同辉光功率条件下系列硅薄膜样品.喇曼测试结果显示:在不同硅烷浓度(SC)条件下,非晶到微晶的过渡区发生在不同的功率点;暗电导随晶化率也体现出不同的变化,此结果表明不同SC、不同功率制备样品的结构特性和电学特性的内在规律是不同的;另外,扫描电子显微镜的测试结果表明样品的表面呈"菜花"状和剖面为柱状的结构特征.

A series of silicon-based samples were fabricated by the very high frequency plasma-enhanced chemical vapor deposition (VHF-PECVD) technique at various discharge powers. The results show that the transition zone occures at different discharge power for silane concentration (SC=[SiH4]/[SiH4+H2]) of 4% and 6%. Furthermore, the dark conductivity also shows different changes with the increase of the crystalline volume fraction, indicating a different relationship between the structural and electrical properties for the samples prepared at different discharge power for the different SC. In addition, the microstructure measurements of the film characterized by scanning electronic microscopy show the evident ‘cauliflower-like' surface morphology and columnar structure.

参考文献

[1] Vetterl O;Hapke P;Kluth O;Lambertz A, .Intrinsic Microcrystalline Silicon for Solar Cells[J].Solid State Phenomena,1999,67-68:101-107.
[2] Meier J.;Dubail S.;Kroll U.;Dubail J.;Golay S. Feitknecht L.;Torres P.;Fay S.;Fischer D.;Shah A.;Vallat-Sauvain E. .Microcrystalline/micromorph silicon thin-film solar cells prepared by VHF-CD technique[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2001(1/4):73-84.
[3] Shah A.;Meier J.;Vallat-Sauvain E.;Droz C.;Kroll U.;Wyrsch N. Guillet J.;Graf U. .Microcrystalline silicon and 'micromorph' tandem solar cells[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2002(0):179-187.
[4] Vetterl O.;Carius R.;Hapke P.;Houben L.;Kluth O.;Lambertz A.;Muck A.;Rech B.;Wagner H.;Finger F. .Intrinsic microcrystalline silicon: A new material for photovoltaics[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2000(1/2):97-108.
[5] Houben L.;Hapke P.;Carius R.;Finger F.;Wagner H.;Luysberg M. .Structural properties of microcrystalline silicon in the transition from highly crystalline to amorphous growth[J].Philosophical Magazine.A.Physics of condensed matter, defects and mechanical properties,1998(6):1447-1460.
[6] Kroll U.;Torres P.;Pohl J.;Shah A.;Meier J. .From amorphous to microcrystalline silicon films prepared by hydrogen dilution using the VHF (70 MHz) GD technique[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1998(Pt.A):68-72.
[7] Wyrsch N.;Droz C.;Torres P.;Shah A.;Poruba A.;Vanecek M.;Feitknecht L. .Hydrogenated microcrystalline silicon: how to correlate layer properties and solar cell performance[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2000(Pt.B):1099-1103.
[8] Ray S.;Mukhopadhyay S.;Jana T.;Carius R. .Transition from amorphous to microcrystalline Si : H: effects of substrate temperature and hydrogen dilution[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2002(Pt.2):761-766.
[9] Ray S.;Das C.;Mukhopadhyay S.;Saha SC. .Substrate temperature and hydrogen dilution: parameters for amorphous to microcrystalline phase transition in silicon thin films[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2002(1/4):393-400.
[10] Droz C;Vollat-Sauvain E;Bailat J;Feitknecht L, Shah A.Application of Raman Spectroscopy for the Microstructure Characterization in Microcrystalline Silicon Solar Cells[A].Munich,2001:2917-2920.
[11] Vetterl O;Carius R;Houben L .Effects of Structural Properties of μc-Si:H Absorber Layers on Solar Cell Performance[J].Materials Research Society Symposium Proceedings,2000,609:5,2,1-1526.
[12] Zhao Y;Miyajima S;Ide Y;Yamada A, Konagai M .Microcrystalline Silicon Films and Solar Cells Prepared by Photochemical Vapor Deposition on Textured SnO2 with High Haze Factors[J].Japanese Journal of Applied Physics,2002,41:417-6420.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%