采用坩埚下降法以及坩埚密封技术,成功生长了直径50mm的新型压电晶体Sr3Ga2Ge4O14.测试了晶体的晶格常数、热膨胀系数、密度、硬度和透过光谱等基本物理性能.测试结果表明:晶体热膨胀系数明显小于石英晶体,而且α11和α33相对比较接近,有利于该晶体用作声表面波用基片材料.在250~2500nm波段范围内,其透过率均大于80%,优于相同结构的La3Ga5SiO14晶体,是一种潜在的激光基质晶体材料.
参考文献
[1] | Takeda H;Kato T;Chani V I .Effect of (Sr, Ba) Substitution in La3 Ga5 SiO14 and La3 Mo.5 Ga5.5 O14 (M = Nb5 + , Ta5 + ) Crystals on Their Synthesis, Structure and Piezoelectricity[J].Journal of Alloys and Compounds,1999,290:79-84. |
[2] | Kumatoriya M.;Nakanishi J.;Fujii T.;Kadota M.;Sakabe Y.;Sato H. .Crystal growth and electromechanical properties of Al substituted langasite (La3Ga5-xAlxSiO14)[J].Journal of Crystal Growth,2001(1):289-293. |
[3] | Sato J.;Morikoshi H.;Shimamura K.;Rudolph P.;Fukuda T.;Takeda H. .Czochralski growth of RE3Ga5SiO14 (RE = La, Pr, Nd) single crystals for the analysis of the influence of rare earth substitution on piezoelectricity[J].Journal of Crystal Growth,1998(4):746-753. |
[4] | 武安华,徐家跃.La3Ga5SiO14单晶的生长、性能及SAW应用[J].人工晶体学报,2002(06):559-564. |
[5] | IWATAKI T;Ohsato H;Tankka T et al.Mechanism of the Piezoelectricity of Langasite Based on the Crystal Structure[J].Journal of the European Ceramic Society,2001,21:1409-1412. |
[6] | 武安华,徐家跃,周娟,范世(马山豆).硅酸镓镧结构的新型压电晶体的研究进展[J].硅酸盐学报,2003(05):480-484. |
[7] | Kochurikhin VV.;Shimamura K.;Takagi H.;Fukuda T.;Kumatoriya M. .CZOCHRALSKI GROWTH OF SR3GA2GE4O14 SINGLE CRYSTALS FOR PIEZOELECTRIC APPLICATIONS[J].Journal of Crystal Growth,1997(4):452-454. |
[8] | Kaminskii A A;Belokoneva E L;Mill B V .Pure and Nd-doped Ca3Ga2Ge4O14 and Sr3Ga2Ge4O14 Single Crystals, Their Structure,Optical, Spectral, Luminescence, Electromechanical Properties, and Stimulated Emission[J].Physica Status Solidi A,1984,86:345-363. |
[9] | Wu X J;Xu J Y;Xiao J Z et al.Growth of Ferroelectric Lead Germinate Single Crystal by the Vertical Bridgman Method[J].Journal of Crystal Growth,2004,263:208-213. |
[10] | 王增梅,袁多荣,潘立虎,张沛霖,李正法,程秀凤,吕衍秋,段秀兰,郭世义,吕孟凯,许东.新型压电晶体La3Ga5SiO14的生长及特性[J].压电与声光,2003(06):490-493. |
[11] | Balda R;Azkargorta J;Iparraguirre I et al.Study of the Cr3 + Sensitization and Structural Disorder Effects on the Nd3 + Laser Action in Cagallogermanate-type Codoped Crystals[J].Optical Materials,1997,8:99-108. |
[12] | 丁嘉瑄,武安华,周娟,徐家跃,范世(马豈).Nd3+:Sr3Ga2Ge4O14晶体的生长及吸收光谱[J].人工晶体学报,2004(03):346-349. |
[13] | Jiaxuan Ding;Anhua Wu;Jiayue Xu .Bridgman growth and defects of Nd~(3+) : Sr_3Ga_2Ge_4O_(14) laser crystals[J].Bulletin of Materials Science,2004(4):333-336. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%