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采用坩埚下降法以及坩埚密封技术,成功生长了直径50mm的新型压电晶体Sr3Ga2Ge4O14.测试了晶体的晶格常数、热膨胀系数、密度、硬度和透过光谱等基本物理性能.测试结果表明:晶体热膨胀系数明显小于石英晶体,而且α11和α33相对比较接近,有利于该晶体用作声表面波用基片材料.在250~2500nm波段范围内,其透过率均大于80%,优于相同结构的La3Ga5SiO14晶体,是一种潜在的激光基质晶体材料.

参考文献

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[5] IWATAKI T;Ohsato H;Tankka T et al.Mechanism of the Piezoelectricity of Langasite Based on the Crystal Structure[J].Journal of the European Ceramic Society,2001,21:1409-1412.
[6] 武安华,徐家跃,周娟,范世(马山豆).硅酸镓镧结构的新型压电晶体的研究进展[J].硅酸盐学报,2003(05):480-484.
[7] Kochurikhin VV.;Shimamura K.;Takagi H.;Fukuda T.;Kumatoriya M. .CZOCHRALSKI GROWTH OF SR3GA2GE4O14 SINGLE CRYSTALS FOR PIEZOELECTRIC APPLICATIONS[J].Journal of Crystal Growth,1997(4):452-454.
[8] Kaminskii A A;Belokoneva E L;Mill B V .Pure and Nd-doped Ca3Ga2Ge4O14 and Sr3Ga2Ge4O14 Single Crystals, Their Structure,Optical, Spectral, Luminescence, Electromechanical Properties, and Stimulated Emission[J].Physica Status Solidi A,1984,86:345-363.
[9] Wu X J;Xu J Y;Xiao J Z et al.Growth of Ferroelectric Lead Germinate Single Crystal by the Vertical Bridgman Method[J].Journal of Crystal Growth,2004,263:208-213.
[10] 王增梅,袁多荣,潘立虎,张沛霖,李正法,程秀凤,吕衍秋,段秀兰,郭世义,吕孟凯,许东.新型压电晶体La3Ga5SiO14的生长及特性[J].压电与声光,2003(06):490-493.
[11] Balda R;Azkargorta J;Iparraguirre I et al.Study of the Cr3 + Sensitization and Structural Disorder Effects on the Nd3 + Laser Action in Cagallogermanate-type Codoped Crystals[J].Optical Materials,1997,8:99-108.
[12] 丁嘉瑄,武安华,周娟,徐家跃,范世(马豈).Nd3+:Sr3Ga2Ge4O14晶体的生长及吸收光谱[J].人工晶体学报,2004(03):346-349.
[13] Jiaxuan Ding;Anhua Wu;Jiayue Xu .Bridgman growth and defects of Nd~(3+) : Sr_3Ga_2Ge_4O_(14) laser crystals[J].Bulletin of Materials Science,2004(4):333-336.
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