本研究工作先用CdCl2和S粉在120℃碱性水溶液中合成了CdS粉末前驱体,再以NaOH为矿化剂,不同的水热条件下分别生长了六方柱和六角片状的CdS晶体.用X射线衍射(XRD)、扫描电子显微镜(SEM)及晶体显微照片对产物进行了表征,并分别探讨了水热条件与晶体形貌、六角片状晶体的大小与生长条件之间的关系.
参考文献
| [1] | Sumiaki Ibuki .On the Crystal Growth of Cadmium Sulphide[J].Journal of the Physical Society of Japan,1959,14(09):1181. |
| [2] | Nesper R .Structure and Chemical Bonding in Zintl-Phases Containing Lithium[J].Progress in Solid State Chemistry,1990,20:1. |
| [3] | Sh(a)fer H.Chemical Transport Reactions[M].New York:Academic Press,1964:31. |
| [4] | Warren C J;Haushalter R C;Bocarsly A B .Electrochemical Synthesis and Structural Characterization of the One-dimensional Chain Compound(Et4N)2[As2Te5]and the Tellurido Arsenate(Me4N)4[As4Te6][J].Chemistry of Materials,1994,6:780. |
| [5] | 蒋民华.面向新世纪的人工晶体[J].人工晶体学报,2001(01):1-9. |
| [6] | G.Dell'Agli;G.Mascolo .Hydrothermal synthesis of ZrO_2-Y_2O_3 solid solutions at low temperature[J].Journal of the European Ceramic Society,2000(2):139-145. |
| [7] | Sekiguchi T.;Obara K.;Shishido T.;Sakagami N.;Miyashita S. .Hydrothermal growth of ZnO single crystals and their optical characterization[J].Journal of Crystal Growth,2000(0):72-76. |
| [8] | 沈德忠.KTP晶体的电光研究进展[J].人工晶体学报,2001(01):28-35. |
| [9] | Wang C;Zhang W X;Qian X F et al.An Aqueous Approach to ZnSe and CdSe Semiconductor Nanocrystals[J].Journal of Materials Chemistry and Physics,1999,60:99-102. |
| [10] | Deng Zhao-Xiang;Li Liao;Li Yadong .Novel Inorganic-organic-layered:Crystallographic Understanding of Both Phase and Morphology Formations of One-dimensional CdE(E=S,Se,Te) Nanorods in Ethylenediamine[J].Inorganic Chemistry,2003,42(07):2331-2341. |
| [11] | Berry LG;Masen B.Mineralogy[M].San FranciscoCalifornia:WH Freeman & CO,1959:351. |
| [12] | 仲维卓;华素坤.晶体生长形态学[M].北京:科学出版社,1999 |
| [13] | 仲维卓.热液条件下晶体的生长基元[J].人工晶体学报,1994(z1):33. |
| [14] | 仲维卓,郑燕青,施尔畏,华素坤.晶体生长溶液、熔体结构与生长基元[J].人工晶体学报,2002(05):425-431. |
| [15] | 华素坤.热液条件下ZnO晶体的形成机理[J].人工晶体学报,1994(03):177. |
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