用二步氧化法可以在草酸或硫酸中制备多孔氧化铝(AAO)模板,这种模板成本低,高度有序,六角排列.利用化学气相沉积技术可以制备高度定向生长的碳纳米管,这将有利于研究碳纳米管的性质和它在纳米电子器件及其他领域的应用.本文介绍了AAO模板的阳极氧化工艺,成膜机理以及不同电解液,氧化电流、电压等因素对纳米孔道的影响.讨论了催化剂和气相沉积温度对碳纳米管特性的影响,并指出这种制备碳纳米管的技术需要深入研究的问题.
参考文献
| [1] | Iijima S .Helical Microtubules of Graphitic Carbon[J].Nature,1991,354(6348):56-58. |
| [2] | Kong J;Franklin N R;Zhou C et al.Nanotube Molecular Wires as Chemical Sensors[J].Science,2000,287(04):622-625. |
| [3] | Xuesong Li;Hongwei Zhu;Lijie Ci;Cailu Xu;Zongqiang Mao;Bingqing Wei;Ji Liang;Dehai Wu .Hydrogen uptake by graphitized multi-walled carbon nanotubes under moderate pressure and at room temperature[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(13):2077-2079. |
| [4] | Che Guangli;Lakshmi B B;Fisher E R et al.Carbon Nanotubule Membranes for Electrochemical Energy Storage and Production[J].Nature,1998,393(6683):346-349. |
| [5] | Guo T.;Thess A.;Colbert DT.;Smalley RE.;Nikolaev P. .CATALYTIC GROWTH OF SINGLE-WALLED NANOTUBES BY LASER VAPORIZATION[J].Chemical Physics Letters,1995(1/2):49-54. |
| [6] | Ebbesen T W;Ajayan P M .Large-scale Synthesis of Carbon Nanotubes[J].Nature,1992,358(6383):220-222. |
| [7] | 王敏炜,彭年才,李凤仪.化学气相沉积法制备碳纳米管的研究进展[J].现代化工,2002(04):18-21. |
| [8] | Deheer WA;Bacsa WS;Chatelain A;Gerfin T;Humphreybaker R;Forro L .ALIGNED CARBON NANOTUBE FILMS - PRODUCTION AND OPTICAL AND ELECTRONIC PROPERTIES[J].Science,1995(5212):845-847. |
| [9] | Z. W. Pan;S. S. Xie;L. Lu;B. H. Chang;L. F. Sun;W. Y. Zhou;G. Wang;D. L. Zhang .Tensile tests of ropes of very long aligned multiwall carbon nanotubes[J].Applied physics letters,1999(21):3152-3154. |
| [10] | Li W Z;Xie S S;Qian L X et al.Large-scale Synthesis of Aligned Carbon Nanotubes[J].Science,1996,274(46):1701-1703. |
| [11] | 潘正伟,常保和,孙连峰,钱露茜,刘祖琴,唐东升,王刚,解思深.超长、开口定向碳纳米管列阵的制备[J].中国科学A辑,1999(08):743-749. |
| [12] | Fan S S;Chapline M G;Granklin N R et al.Self-oriented Regular Arrays of Carbon Nanotubes and Their Field Emission Properties[J].Science,1999,283(04):512-514. |
| [13] | 徐东升,郭国霖,桂琳琳,唐有祺,施祖进,金朝霞,顾振南.以多孔硅为模板制备取向碳纳米管[J].中国科学B辑,2000(04):289-293. |
| [14] | Dongsheng Xu;Guolin Guo;Linlin Gui .Controlling growth and field emission property of aligned carbon nanotubes on porous silicon substrates[J].Applied physics letters,1999(4):481-483. |
| [15] | Jerry L.Patel;Nannaji Saka .Microplasmic Coatings[J].American Ceramic Society bulletin,2001(4):27-29. |
| [16] | Hoyer P;Baba N;Masuda H .Small Quantum-sized CdS Particles Assembled to Form a Regularly Nanostructured Porous Film[J].Applied Physics Letters,1995,66(20):2700-2702. |
| [17] | Jinxia Xu;Xinming Huang;Guozhi Xie;Yonghao Fang;Dazhi Liu .Study on the structures and magnetic properties of Ni,Co-Al_2O_3 electrodeposited nanowire arrays[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2004(6):811-818. |
| [18] | 王爱华;管荻华;周维亚 等.以多孔硅为模板制备取向碳纳米管[J].无机化学学报,2002,18(05):447-450. |
| [19] | 赵兵;蔡林涛;顾宁 .阳极氧化法制备多孔氧化铝膜的研究[J].东南大学学报(自然科学版),1999,29(06):45. |
| [20] | 王红波,王森,俞国军,李玉兰,何绥霞,巩金龙,陆荣荣,朱德彰,朱志远.高度定向的碳纳米管阵列的制备[J].核技术,2004(09):676-680. |
| [21] | Jung Sang Suh;Jin Seung Lee .Highly ordered two-dimensional carbon nanotube arrays[J].Applied Physics Letters,1999(14):2047-2049. |
| [22] | Y.C.Sui;J.A.Gonzalez-Leon;A.Bermudez;J.M.Saniger .Synthesis of multi branched carbon nanotubes in porous anodic aluminum oxide template[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(11):1709-1715. |
| [23] | 王成伟,李梦柯,潘善林,力虎林.用多孔氧化铝模板制备高度取向碳纳米管阵列膜的研究[J].科学通报,2000(05):493-497. |
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