水热法合成Zn1-xMnxO稀磁半导体

人工晶体学报, 2006, 35(1): 95-103. doi: 10.3969/j.issn.1000-985X.2006.01.021

水热法合成Zn1-xMnxO稀磁半导体

韦志仁 ^1, , 刘超 ^2, , 李军 ^3, , 葛世艳 ^4, , 张华伟 ^5, , 林琳 ^6, , 郑一博 ^7, , 窦军红 ^8,

1.河北大学物理科学与技术学院,保定,071002

2.河北大学物理科学与技术学院,保定,071002

3.河北大学物理科学与技术学院,保定,071002

4.河北大学物理科学与技术学院,保定,071002

5.河北大学物理科学与技术学院,保定,071002

6.河北大学物理科学与技术学院,保定,071002

7.河北大学物理科学与技术学院,保定,071002

8.河北大学物理科学与技术学院,保定,071002

基金项目: Natural Science Foundation of China(50472037) the Science and Technology Research Program and Bureau of Science and Technology of Hebei Province(2002158) 河北省教育厅科研项目(E2004000117,F2004000130)

关键词：水热合成 , 氧化锌 , 稀磁半导体

Hydrothermal Synthesis of Diluted Magnetic Zn1-xMnxO Semiconductor

Keywords： hydrothermal synthesis , ZnO , diluted magnetic semiconductor

本文采用水热法在430℃,以3mol%·L-1KOH作矿化剂,填充度为35%,反应时间24h,合成了Zn1-xMnxO稀磁半导体晶体.所合成晶体具有ZnO纤锌矿结构,晶面显露正极面{0001}、负极面{0001}、菱面{1011}及负菱面{1011}晶体高度为5～30μm,径高比约为2:1.X荧光能谱(EDS)显示Mn原子百分浓度为2.6%(x=0.026).晶体呈现低温铁磁性,居里温度50K.

Diluted magnetic semiconductor Zn1-x MnxO crystals were synthesized at 430℃ for 24h by obtained crystals show a ZnO wurtzite structure, with positive polar faces {0001} , negative polar faces{0001-}, p faces {-1011} and -p faces { -1011- }exposed. The height of the crystal is 5-30μm and radiusheight ratio is 2: 1. Mn atom concentration of 2.6% ( x = 0. 026 ) was determined using X-ray energy dispersive spectroscopy (EDS). The crystals show low-temperature ferromagnetism with Curie temperature of 5OK.

参考文献

[1]	Matsumoto Y J;Murakami M;Shono T J;Hasegawa T Y, Fukumura T T, Kawasaki M S, Ahmet P, Chikyow T H, Koshihara S Y, Koinuma H O .Room-temperature Ferromagnetism in Transparent Transition Metal-doped Titanium Dioxide[J].Science,2001,291:854-856.
[2]	Dietl T;Ohno H;Matsukura F;Cibert J, Ferrand D .Zener Model Description of Ferromagnetism in Zinc-blende Magnetic Semiconductors[J].Science,2000,287:1019-1022.
[3]	Parmanand Sharma;Amita Gupta;Amita Gupta;K.V.Rao;Frank J.Owens;Renu Sharma;Rajeev Ahuja;J.M.Osorio Guillen;Borje Johansson;G.A.Gehring .Ferromagnetism above room temperature in bulk and transparent thin films of Mn-doped ZnO[J].Nature materials,2003(10):673-677.
[4]	Dietl T Dilute .Magnetic Semiconductors:Functional ferromagnets[J].Nature Materials,2003,2(10):646.
[5]	Chiba D.;Yamanouchi M.;Matsukura F.;Ohno H. .Electrical manipulation of magnetization reversal in a ferromagnetic semiconductor[J].Science,2003(5635):943-945.
[6]	Park Y D;Hanbicki A T;Erwin S C;Hellberg C S, Sullivan J M, Mattson J E, Ambrose T F, Wilson A, Spanos G, Jonker B T .A Group-ⅣFerromagnetic Semiconductor:MnxGelx[J].Science,2002,295:651.
[7]	Ohno H .Making Nonmagnetic Semiconductors Ferromagnetic[J].Science,1998,281:951.
[8]	Ando K.;Jin ZW.;Fukumura T.;Kawasaki M.;Matsumoto Y. Koinuma H.;Saito H. .Magneto-optical properties of ZnO-based diluted magnetic semiconductors[J].Journal of Applied Physics,2001(11 Pt.2):7284-7286.
[9]	S. W. Jung;S.-J. An;Gyu-Chul Yi;C. U. Jung;Sung-Ik Lee;Sunglae Cho .Ferromagnetic properties of Zn_(1-x)Mn_(x)O epitaxial thin films[J].Applied physics letters,2002(24):4561-4563.
[10]	Chang Y Q;Wang D B;Luo X H;Xu X Y, Chen X H, Li L, Chen C P, Wang R M, Xu J, Yu D P .Synthesis,Optical and Magnetic Properties of Diluted Magnetic Semiconductor Zn1-xMnxO Nanowires via Vapor Phase Growth[J].Applied Physics Letters,2003,83:4020.
[11]	Chang YQ;Xu XY;Luo XH;Long Y;Ye RC .Magnetic properties of diluted magnetic semiconductor Zn1-xMnO nanowires[J].Chinese physics letters,2005(4):991-994.
[12]	常永勤,罗旭辉,徐向宇,李琳,陈晋平,王荣明,俞大鹏.Synthesis, Characterization and Magnetic Property Measurements of Zn1-xMnxO Nanoparticles via Vapour Phase Growth[J].中国物理快报(英文版),2003(11):2058-2060.
[13]	RoyVAL;DjuriiA B;LiuH;Zhang X X, Leung Y H, Xie M H, GaoJ, Lui H F, Surya C .Magnetic Properties of Mn Doped ZnO Tetrapod Structures[J].Applied Physics Letters,2004,84:756-758.
[14]	D. P. Norton;S. J. Pearton;A. F. Hebard;N. Theodoropoulou;L. A. Boatner;R. G. Wilson .Ferromagnetism in Mn-implanted ZnO:Sn single crystals[J].Applied physics letters,2003(2):239-241.
[15]	Ip K et al.Ferromagnetism in Mn-and Co-implanted ZnO Nanorods[J].Journal of Vacuum Science and Technology,2003,B21:1476.
[16]	Kim JY.;Park JH.;Park BG.;Noh HJ.;Oh SJ.;Yang JS.;Kim DH.;Bu SD. Noh TW.;Lin HJ.;Hsieh HH.;Chen CT. .Ferromagnetism induced by clustered Co in Co-doped anatase TiO2 thin films - art. no. 017401[J].Physical review letters,2003(1):7401-0.
[17]	Jung H. Park;Min G. Kim;Hyun M. Jang;Sangwoo Ryu;Young M. Kim .Co-metal clustering as the origin of ferromagnetism in Co-doped ZnO thin films[J].Applied physics letters,2004(8):1338-1340.
[18]	Lee Un-C;Chang K J .Ferromagnetic versus Antiferromagnetic Interaction in Co-doped ZnO[J].Physical Review B,2004,69:085205.
[19]	Clusters and magnetism in epitaxial Co-doped TiO_(2) anatase[J].Applied physics letters,2003(8):1257-1259.
[20]	Ando K .Magneto-optical Studies of s,p-d Exchange Interactions in GaN:Mn with Room-temperature Ferromagnetism[J].Applied Physics Letters,2003,82:100.
[21]	Possible origin of ferromagnetism in (Ga,Mn)N[J].Journal of Applied Physics,2003(8):4715-4717.
[22]	S. Kolesnik;B. Dabrowski;J. Mais .Structural and magnetic properties of transition metal substituted ZnO[J].Journal of Applied Physics,2004(5):2582-2586.
[23]	Sang Sub Kim;Jong Ha Moon;Byung-Teak Lee;Oh Sung Song;Jung Ho Je .Heteroepitaxial growth behavior of Mn-doped ZnO thin films on Al_(2)O_(3) (0001) by pulsed laser deposition[J].Journal of Applied Physics,2004(2):454-459.
[24]	Han S J;Jang T H;Kim Y B;Park B G, Park J H, Jeong Y H .Magnetism in Mn-doped ZnO Bulk Samples Prepared by Solid State Reaction[J].Applied Physics Letters,2003,83:920-922.
[25]	Cheng XM.;Chien CL. .Magnetic properties of epitaxial Mn-doped ZnO thin films[J].Journal of Applied Physics,2003(10 Pt.3):7876-7878.
[26]	Sakagami N.;Sekiguchi T.;Miyashita S.;Obara K.;Shishido T.;Yamashita M. .Variation of electrical properties on growth sectors of ZnO single crystals[J].Journal of Crystal Growth,2001(1):98-103.
[27]	Sekiguchi T.;Obara K.;Shishido T.;Sakagami N.;Miyashita S. .Hydrothermal growth of ZnO single crystals and their optical characterization[J].Journal of Crystal Growth,2000(0):72-76.
[28]	Suscavage M.High-quality Hydrothermal ZnO Crystals[A].Boston,Massachusetts,U.S.A
[29]	Eriko Ohshima;Hiraku Ogino;Ikuo Niikura;Katsumi Maeda;Mitsuru Sato;Masumi Ito;Tsuguo Fukuda .Growth of the 2-in-size bulk ZnO single crystals by the hydrothermal method[J].Journal of Crystal Growth,2004(1/2):166-170.
[30]	Liu B;Zeng H C;Ji Y L;Guo L .Hydrothermal Synthesis of ZnO Nanorods in the Diameter Regime of 50nm[J].Journal of the American Chemical Society,2003,125(15):4430-4431.
[31]	Ji Y L;Guo L;Xu H;Simon P, Wu Z .Single-crystalline ZnO Nanorods with Wurtzite Structure[J].Journal of the American Chemical Society,2002,124(50):14864-14865.
[32]	Jin-Ho Choy;Eue-Soon Jang;Jung-Hee Won;Jae-Hun Chung;Du-Jeon Jang;Young-Woon Kim .Hydrothermal route to ZnO nanocoral reefs and nanofibers[J].Applied physics letters,2004(2):287-289.
[33]	Wang BG.;Zhong WZ.;Shi EW. .Twinning morphologies and mechanisms of ZnO crystallites under hydrothermal conditions[J].Crystal Research and Technology: Journal of Experimental and Industrial Crystallography,1998(6):937-941.
[34]	Zhiren Qiu;K. S. Wong;Mingmei Wu;Wenjiao Lin;Huifang Xu .Microcavity lasing behavior of oriented hexagonal ZnO nanowhiskers grown by hydrothermal oxidation[J].Applied physics letters,2004(15):2739-2741.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网