利用热重试验研究了表面沉积有ZnCl12和ZnCl2+KCl盐膜的20钢在450℃流动氧气中的腐蚀行为。20钢在单纯氧气中具有很低的氧化增重,涂盐条件下加速腐蚀,氧化层明显变厚,而ZnCl2+KCl比在单一ZnCl2盐膜下腐蚀更为严重,在氧化膜/合金界面均检测到金属氯化物,在基体局部区域还出现球状的含氯腐蚀产物,讨论了合金在盐膜下的加速腐蚀机理。
The corrosion behavior of 20 steel beneath ZnCl2 and ZnCl2 + KCl deposits in flowing O2 was studied by means of thermogravimetric experiment. 20 steel was oxidized very slowly in pure O2, whereas a significantly accelerated corrosion was observed in the presence of salt deposition, and the corrosion was more serious in ZnCl2 + KCl mixture than in ZnCl2 . Iron chloride was also detected at the interface of oxide and metal matrix. The effect of the salts on the corrosion mechanism was discussed.
参考文献
[1] | Spiegel M;GralkeHJ .High temperature corrosion of high alloy steelsin simulated waste incineration environments[J].Materials and Corrosion,1996,47:179. |
[2] | Nakagawa K;Matsunaga Y .The effects of chemical composition of ash deposits on the corrosion of boiler tubes in waste incinerators[J].Materials Science Forum,1997,55:251-254. |
[3] | 李远士,牛焱,刘刚,吴维(山文).金属材料在垃圾焚烧环境中的高温腐蚀[J].腐蚀科学与防护技术,2000(04):224-227. |
[4] | 李远士;王富岗;牛焱 等.燃煤发电厂中的高温腐蚀问题及防护[J].全面腐蚀控制,1999,13(03):8. |
[5] | 李远士,牛焱,吴维(山文).金属材料的高温氯化腐蚀[J].腐蚀科学与防护技术,2000(01):41-44. |
[6] | GrabkeHJ;Reese E;Spiegel M .The effect of chlorine, hydrogen chloride, and sulfur dioxide in the oxidation of steels below deposts[J].Corrosion Science,1995,37:1023. |
[7] | Sorell G .The role of cholrine in high temperature corrosion in waste-to-en ergy plants[J].Materials at High Temperatures,1997,14:207. |
[8] | MillerPD;KrauseHH;VaughanDAetal .The mechanism in high temperature corrosion in municipal incinerators[J].Corrosion,1972,28:274. |
[9] | Spiegel M;Grabke H J .Salt melt induced corrosion of metallic materials inwaste incineration plants[J].Materials and Corrosion,1999,50:373. |
[10] | Schmalzried H .Grundsatzliche Uberlegungen zur Spinellbildung in Zunder schichten und zun den Transporteigenschaften der Spinelle[J].Werkstoffe und Korrosion,1971,22:371. |
[11] | HossainMK;SaundersSRJ .Amicrosturucture study of the in fluence of NaCl vapor on the oxidation ofa Ni-Cr-Al alloys at 850 ℃[J].Oxidation of Metals,1978,12:1. |
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