欢迎登录材料期刊网

材料期刊网

高级检索

利用热分解法制备了不同La含量的钛基Ru-La-Ti涂层阳极,并研究了所制备涂层的电催化性能.结果表明,在Ru-Ti涂层阳极中掺杂稀土元素La可以提高涂层阳极的电催化活性,且La的掺杂量存在一个最佳范围(La的摩尔分数0.2).涂层阳极电催化活性提高的原因在于La的引入可以提高涂层的有效活性表面积.

参考文献

[1] Farla L A;Boodta J F C;Trasatti S .Physical-Chemical and Electrochemical Characterization of Ru-Based Ternary Oxides Containg Ti and Ce[J].Electrochimica Acta,1992,37(13):2511-2518.
[2] Depauli CP.;Trasatti S. .ELECTROCHEMICAL SURFACE CHARACTERIZATION OF IRO2+SNO2 MIXED OXIDE ELECTROCATALYSTS[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,1995(1/2):161-168.
[3] Dasilva LA.;Trasatti S.;Boodts JFC.;Alves VA. .SURFACE AND ELECTROCATALYTIC PROPERTIES OF TERNARY OXIDES IR0.3TI(0.7-X)PTXO2 - OXYGEN EVOLUTION FROM ACIDIC SOLUTION[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,1997(1/2):97-104.
[4] Yasushi M;Takeshi K;Yoshihiro S .Effects of Rare Earth Chlorides on the Preparation of Porous Ruthenium Oxide Electrodes[J].Journal of Alloys and Compounds,1996,239:111-113.
[5] Faria L A .Electrocatalytic Properties of Ternary Oxides Ru0.3Ti(0.7-x)CexO2:Oxygen Evolution from Acidic Solution[J].Journal of Applied Electrochemistry,1996(26):1195-1199.
[6] Correalozano B.;Debattisti A.;Comninellis C. .ELECTROCHEMICAL PROPERTIES OF TI/SNO2-SB2O5 ELECTRODES PREPARED BY THE SPRAY PYROLYSIS TECHNIQUE[J].Journal of Applied Electrochemistry,1996(7):683-688.
[7] Deng T S;Bing J H .Morphology and Electrochemical Activity of Ru-Ti-Sn Ternary-Oxide Electrodes in 1 mol/L NaCl Solution[J].Electrochimica Acta,1993,38(15):2329-2346.
[8] Lassali T A;Boodts J F;Bulhoes L O.Charging Processes and Electrocatalytic Properties of IrO2/TiO2/SnO2 Oxide Films Investigated by in Situ AC Impedance Measurements[J].Electrochimica Acta,1999:44.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%