研究了电镀锌板上一种新型ca2+、Zn2+、Mn2+三元磷化工艺.通过扫描电镜(SEM)、光电子能谱(XPS)、电化学交流阻抗等方法研究了Ca2+浓度对磷化膜晶粒形态、膜层结构及膜层耐腐蚀性能的影响.采用时间电位曲线和扫描电镜(SEM)分析研究了这种新型三元磷化膜在镀锌板上的生长机理且与传统zn2+、Mn2+、Ni2+三元磷化膜微观形态及耐蚀性能进行了比较.结果表明,在最佳Ca2+浓度下,电镀锌板上三元磷化膜具有类似钢铁表面粒状磷化膜的微观形态,比传统三元磷化膜晶粒结构更细致、耐蚀性更好.
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