以不同性质的硅铝陶瓷材料为支撑基材,经基面修饰后,采用溶胶-凝胶法制备支撑β-沸石膜.通过实验研究了基材表面的硅铝比以及基面修饰条件对形成β-沸石膜的影响,并采用XRD和SEM对膜进行了表征.结果表明:支撑β-沸石膜的晶体形貌及晶体大小均与支撑基材的表面性质有关.在不同硅铝比的基材表面所生长出的β-沸石晶体膜的形貌不同.在Al2O3表面形成的β-沸石为长条形晶体,而在硅铝陶瓷基材表面上形成的β-沸石为立方颗粒晶体.基材表面的Si-OH基要比Al-OH基更加有利于在表面生长出较小晶体尺寸的β-沸石膜.另外,在硅铝陶瓷基材表面酸处理要比碱处理更有利于β-沸石膜的生长.
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