综述了液相法合成纳米TiO2粉体的各种方法,评述了液相沉淀法、水解法、溶胶-凝胶法、水热法、微乳液法和液相一步合成法的制备工艺及特点,并指出液相一步合成法在常压低温下就能合成团聚小、单分散性好和光催化活性高的金红石相纳米TiO2粉体,此生产工艺由于省去了高温焙烧工序而最具竞争力.
参考文献
| [1] | 姚超,吴凤芹,林西平,汪信.纳米技术与纳米材料（Ⅸ）--纳米TiO2的液相合成[J].日用化学工业,2004(03):190-194,197. |
| [2] | 李国华,王大伟,徐铸德,黄志良,陈卫祥.不同沉淀剂制备的纳米氧化钛粉体晶相控制[J].硅酸盐学报,2003(03):272-277,299. |
| [3] | 丁珂,田进军,王晟,叶庆国.液相沉淀法制备纳米TiO2及其光催化性能的研究[J].工业催化,2004(10):30-33. |
| [4] | 何超,于云,周彩华,胡行方,Ande LARBOT.Ag掺杂对TiO2粉末结构的影响[J].无机材料学报,2003(02):457-464. |
| [5] | 文明芬,王秋萍,陈靖,景山,宋崇立.纳米二氧化钛晶型互变的研究[J].功能材料,2004(05):651-653. |
| [6] | Zhang X;Zhang F;Chan KY .Synthesis of titania-silica mixed oxide mesoporous materials, characterization and photocatalytic properties[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2005(1/2):193-198. |
| [7] | Fang CS.;Chen YW. .Preparation of titania particles by thermal hydrolysis of TiCl4 in n-propanol solution[J].Materials Chemistry and Physics,2003(3):739-745. |
| [8] | 徐建春,储伟,王安,邱发礼.受控水解法制备纳米TiO2光催化剂及其结构性能[J].化学研究与应用,2005(03):389-391. |
| [9] | Ki Chang Song;Sotiris E. Pratsinis .Control of Phase and Pore Structure of Titania Powders Using HCl and NH_4OH Catalysts[J].Journal of the American Ceramic Society,2001(1):92-98. |
| [10] | 陈文新,黄浪欢,刘应亮,王朋,张静娴,容建华,汤丽娜.微波法制备纳米TiO2[J].化学研究与应用,2004(05):661-663. |
| [11] | Koshitani N;Sakulkhaemaruethai S;Suzuki Y et al.Preparation of mesoporous titania nanocrystals using alkylamine surfactant templates[J].Ceramics International,2005,2207:1-6. |
| [12] | Sakulkhaemaruethai S;Pavasupree S;Suzuki Y et al.Photocatalytic activity of titania nanocrystals prepared by surfactant-assisted templating method-Effect of calcination conditions[J].Materials Letters,2005,59:2965-2968. |
| [13] | Thammanoon Sreethawong;Yoshikazu Suzuki;Susumu Yoshikawa .Photocatalytic evolution of hydrogen over nanocrystalline mesoporous titania prepared by surfactant-assisted templating sol-gel process[J].Catalysis Communications,2005(2):119-124. |
| [14] | Senthilkumaar S;Porkodi K;Vidyalakshmi R .Photodegradation of a textile dye catalyzed by sol-gel derived nanocrystalline TiO2 via ultrasonic irradiation[J].Journal of Photochemistry and Photobiology, A. Chemistry,2005(3):225-232. |
| [15] | Kolen'ko YV;Churagulov BR;Kunst M;Mazerolles L;Colbeau-Justin C .Photocatalytic properties of titania powders prepared by hydrothermal method[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2004(1):51-58. |
| [16] | Kaifeng Yu;Jingzhe Zhao;Xu Zhao .Self-assembly and oriented organization of shape-controlled nanocrystalline TiO_2[J].Materials Letters,2005(21):2676-2679. |
| [17] | Seong-Soo Hong;Man Sig Lee;Chang-Sik Ju;Gun-Dae Lee;Seong Soo Park;Kwon-Taek Lim .Photocatalytic decomposition of p-nitrophenol over titanium dioxides prepared in water-in-carbon dioxide microemulsion[J].Catalysis Today,2004(0):871-876. |
| [18] | 牛新书,许亚杰,张学治,刘国光,蒋凯.微乳液法制备纳米二氧化钛及其光催化活性[J].功能材料,2003(05):548-549,552. |
| [19] | Lee MS;Lee GD;Ju CS;Hong SS .Preparations of nanosized TiO2 in reverse microemulsion and their photocatalytic activity[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2005(4):389-401. |
| [20] | Lee M S;Park S S;Lee G D et al.Synthesis of TiO2 particles by reverse microemulsion method using nonionic suffactants with different hydrophilic and hydrophobic group and their photocatalytic activity[J].Catalysis Today,2005,101:283-290. |
| [21] | 孙静,高濂,张青红.制备具有光催化活性的金红石相纳米氧化钛粉体[J].化学学报,2003(01):74-77. |
| [22] | Yang SF.;Liu YH.;Guo YP.;Zhao JZ.;Xu HF.;Wang ZC. .Preparation of rutile titania nanocrystals by liquid method at room temperature[J].Materials Chemistry and Physics,2003(2):501-506. |
| [23] | Li Y Z;Lee N H;Lee E G et al.The characterization and photocatalytic properties of mesoporous rutile TiO2 powder synthesized through selfassembly of nano crystals[J].Chemical Physics Letters,2004,389:124-128. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%