近年来,一种新的氧离子导体-磷灰石型氧化物被发现,其结构和氧离子传输方式都不同于目前已发现的几种氧离子导体(如萤石型ZrO2、钙钛矿型氧化物等),在低温下就显示出了高离子电导率和低活化能,使固体氧化物燃料电池在低温下工作成为可能.本文就近年来国外对磷灰石型电解质材料结构和性能的研究进展进行了综述.
参考文献
| [1] | Ellen Ivers-Tiffee;Andre Weber;Dirk Herbstritt .Materials and technologies for SOFC-components[J].Journal of the European Ceramic Society,2001(10/11):1805-1811. |
| [2] | Lee JH;Kim J;Kim SW;Lee HW;Song HS .Characterization of the electrical properties of Y2O3-doped CeO2-rich CeO2-ZrO2 solid solutions[J].Solid state ionics,2004(1/2):45-52. |
| [3] | 魏丽,陈诵英,王琴.中温固体氧化物燃料电池电解质材料的研究进展[J].稀有金属,2003(02):286-292,298. |
| [4] | 孙明涛,孙俊才,季世军.固体氧化物燃料电池的中低温化研究[J].稀有金属,2004(06):1065-1069. |
| [5] | Nakayama S;Kageyama T;Aono H et al.Ionic conductivity of lanthanoid silicates,Ln10(SiO4)6O3(Ln= La,Nd,Sm,Gd,Dy,Y,Ho,Er and Yb)[J].Journal of Materials Chemistry,1995,5:1801-1805. |
| [6] | Susumu N;Masatomi S .Electrical properties of new type high oxide ionic conductor RE10Si6O27(RE = La,Pr,Nd,Sm,Gd,Dy)[J].Journal of the European Ceramic Society,1998,18:1413-1418. |
| [7] | Yaremchenko AA;Shaula AL;Kharton VV;Waerenborgh JC;Rojas DP;Patrakeev MV;Marques FMB .Ionic and electronic conductivity of La9.83-xPrxSi4.5Fe1.5O26 +/-delta apatites[J].Solid state ionics,2004(1/2):51-59. |
| [8] | Arikawa H.;Ishihara T.;Takita Y.;Nishiguchi H. .Oxide ion conductivity in Sr-doped La10Ge6O27 apatite oxide[J].Solid state ionics,2000(Special Issue SI):31-37. |
| [9] | Slater P R;Sansom J E H;Tolchard J R.The synthesis and characterisation of Ge containing apatite-type oxide ion conductors[A].,2003:756. |
| [10] | Sansom JEH;Slater PR .Oxide ion conductivity in the mixed Si/Ge apatite-type phases Lag(9.33)Si(6-x)Ge(x)O(26)[J].Solid state ionics,2004(1/2):23-27. |
| [11] | Sansom J E H;Najib A;Slater P R .Oxide ion conductivity in mixed Si/Ge-based apatite-type systems[J].Solid State Ionics,2004,175:353-355. |
| [12] | Leon-Reina, L;Losilla, ER;Martinez-Lara, M;Martin-Sedeno, MC;Bruque, S;Nunez, P;Sheptyakov, DV;Aranda, MAG .High oxide ion conductivity in Al-doped germanium oxyapatite[J].Chemistry of Materials,2005(3):596-600. |
| [13] | Shanla A L;Kharton V V;Marques F M B .Oxygen ionic and electronic transport in apatite-type La10-x(Si,Al)6O26±δ[J].Journal of Solid State Chemistry,2005,178:2050-2061. |
| [14] | Sansom JEH;Tolchard JR;Slater PR;Islam MS .Synthesis and structural characterisation of the apatite-type phases La10-xSi6O26+z doped with Ga[J].Solid state ionics,2004(1/2):17-22. |
| [15] | Tolchard JR;Sansom JEH;Islam MS;Slater PR .Structural studies of apatite-type oxide ion conductors doped with cobalt[J].Dalton transactions: An international journal of inorganic chemistry,2005(7):1273-1280. |
| [16] | A.L. Shaula;V.V. Kharton;J.C. Waerenborgh .Oxygen Ionic and electronic transport in apatite ceramics[J].Journal of the European Ceramic Society,2005(12):2583-2586. |
| [17] | Najib A;Sansom JEH;Tolchard JR;Slater PR;Islam MS .Doping strategies to optimise the oxide ion conductivity in apatite-type ionic conductors[J].Dalton transactions: An international journal of inorganic chemistry,2004(19):3106-3109. |
| [18] | Nakayama S;Higuchi Y;Kondo Y;Sakamoto M .Effects of cation- or oxide ion-defect on conductivities of apatite-type La-Ge-O system ceramics[J].Solid state ionics,2004(3/4):219-223. |
| [19] | Sansom JEH.;Slater PR.;Richings D. .A powder neutron diffraction study of the oxide-ion-conducting apatite-type phases, La9.33Si6O26 and La8Sr2Si6O26[J].Solid state ionics,2001(3/4):205-210. |
| [20] | Tolchard JR.;Islam MS.;Slater PR. .Defect chemistry and oxygen ion migration in the apatite-type materials La9.33Si6O26 and La8Sr2Si6O26[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(8):1956-1961. |
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