为了考察镁砂与铬矿间的反应过程及其特征,以高纯镁砂颗粒和西藏铬矿细粉为原料,在200 MPa下制成50 mm×20 mm的试样,然后在高温隧道窑中于1 750 ℃烧成,并对烧成后的试样进行BSE和EDS分析.结果表明:随着距离镁砂-铬矿边界距离的增加,镁砂颗粒内部Cr、Fe、Al的质量分数均减少,镁砂颗粒边缘富含Fe,颗粒内部Cr含量较高.镁砂-铬矿边界呈直接结合,镁砂内的尖晶石相分布较均匀.
参考文献
[1] | Goto K.;Lee WE. .THE DIRECT BOND IN MAGNESIA CHROMITE AND MAGNESIA SPINEL REFRACTORIES[J].Journal of the American Ceramic Society,1995(7):1753-1760. |
[2] | Marrington Jr G W;Treffner W S .Direct-bonded(MgO-Cr2O3) refractory bricks[P].US 3829541,1974. |
[3] | White J.Magnesia-based refractories in high temperature oxides Part 1 magnesia,lime,and chrome refractories[M].New York:Academic Press,Inc,1970:143-187. |
[4] | Carter R E .Mechanism of solid-state reaction between magnesium oxide and aluminum oxide and between magnesium oxide and ferric oxide[J].Journal of the American Ceramic Society,1961,44(03):116-120. |
[5] | Paik JG;Lee MJ;Hyun SH .Reaction kinetics and formation mechanism of magnesium ferrites[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2005(1/2):131-136. |
[6] | Hulbert S F;Brosnan D A;Smoak R H.Kinetics and mechanism of the reaction between MgO and Cr2O3 in reactivity of solids[M].New York:Wiley-Interscience,1968:573-584. |
[7] | M.K. Haldar;H.S. Tripathi;S.K. Das .Effect of compositional variation on the synthesis of magnesite-chrome composite refractory[J].Ceramics International,2004(6):911-915. |
[8] | Y. Mercankoesk;S. Akkurt;M. Ciftcioglu .Microstructural Characterization of Industrial Chromite and Spinel Cement Kiln Refractories with Emphasis on the Iron-rich Rims[J].Key engineering materials,2004(3):1763-1766. |
[9] | Shewmon P G.Diffusion in solids[M].New York:McGraw-Hill,1963:151-180. |
[10] | Zubakov S M .Interaction between chromite and magnesium oxide when heated[J].Refrac Ind Ceram,1960,1(5-6):220-225. |
[11] | Murthy K S R C;Ghose J;Rao E N.Reactivity in the spinel formation reaction in CuO/Al2O3,Fe2O3,Cr2O3 systems[J].Journal of Materials Science Letters,1983(02):393-394. |
[12] | Menezes I de;Stubican V S .Grain-boundary reactions in magnesia-chrome refractories:application of the electron probe Ⅱ[J].Journal of the American Ceramic Society,1966,49(11):609-612. |
[13] | Kohn S C .A mechanism for reaction between magnesium oxide and a natural chromite at 1 530 ℃[J].Materials Science Forum,1986,7:133-138. |
[14] | 程继健 .尖晶石合成的若干规律[J].硅酸盐学报,1959,1(04):201-210. |
[15] | Montgomery T S .Lattice spacings of periclase-chromite solid solutions[J].Journal of the American Ceramic Society,1969,52(01):59-60. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%