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采用特级高铝矾土熟料、红柱石、SiO2微粉及α-Al2 O3微粉为主要原料,以Secar71水泥为结合剂,固定骨料与细粉质量比为6535,且固定粉料中SiO2微粉与α-Al2 O3微粉的总加入量(w)为8%,研究了仅改变两种微粉的加入比例(α-Al2O3微粉的加入量(w)分别为8%、6%、4%、2%、0,SiO2微粉相应为0、2%、4%、6%、8%)对试样的流动性、高温强度、物相组成和显微结构的影响。结果表明:当α-Al2 O3微粉、SiO2微粉加入量(w)各为4%时,其流动性最佳,此时体系在高温下生成了大量的一次莫来石相,针状莫来石晶体穿插在刚玉骨架之间,使材料的常温抗折强度以及抗热震性最优。

The specimens were prepared using special grade bauxite clinker,andalusite,SiO2 micropowder and α-Al2O3 micropowder as main starting materials and Secar71 cement as binder.The mass ratio of ag-gregate to fines was 65 35 and the total addition of SiO2 micropowder and α-Al2 O3 micropowder was fixed at 8% (in mass,the same hereinafter),addition of α-Al2 O3 micropowder was 8%,6%,4%,2% and 0,re-spectively.Effects of adjusting additions of the two micropowders on the flowability,hot strength,phase composition and microstructure were researched.The results show that:when the additions of SiO2 mi-cropowder and α-Al2 O3 micropowder are both 4%,the specimen performs the best flowability;a lot of nee-dle like mullite crystals form at high temperatures,crossing into the corundum skeleton,endowing the mate-rials with the optimal cold modulus of rupture and thermal shock resistance.

参考文献

[1] 张惠敏,汪立今,贾殿赠.红柱石材料领域的应用及其研究新进展[J].新疆大学学报(自然科学版),2006(01):53-57.
[2] 王龙光,刘鹏,周会俊,张立明,王冬冬,娄海琴.红柱石微粉加入量对红柱石材料结构与性能的影响[J].耐火材料,2010(03):202-204.
[3] Sako E Y;Braulio M A L;Bittencourt L R M et al.The impact of pre-formed and in situ spinel formation on the physical properties of cement-bonded high alumina refractory castables[J].CERAMICS INTERNATIONAL,2012,36(07):2079-2085.
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