欢迎登录材料期刊网

材料期刊网

高级检索

为了提高泡沫陶瓷浆料的稳定性,进而制备出高孔隙率的泡沫陶瓷,采用没食子酸正丙脂(PG)修饰α-Al2 O3微粉颗粒,使其具有部分疏水性,采用发泡-冷冻干燥法制备了Al2 O3多孔陶瓷材料,主要研究了PG加入量(w,0.1%~2.0%)、料浆固含量(w,49.0%~61.9%)和烧成温度(1300~1500℃)对Al2O3多孔陶瓷材料性能的影响。结果表明:以没食子酸正丙脂(PG)作修饰剂,对α-Al2 O3微粉颗粒稳定气泡有良好的作用;当PG加入量为1.5%(w),固含量为58%(w),烧成温度为1500℃时,制备的Al2 O3多孔陶瓷材料的显气孔率为72%,体积密度为0.59 g·cm-3,耐压强度为12.5 MPa。

To enhance the stabilization of foam ceramic slurries and prepare foam ceramics with high porosi-ty,the porous Al2 O3 ceramics were prepared by foaming-freeze drying method using propyl gallate (PG) modified α-Al2 O3 micropowder with partial hydrophobicity.Effects of PG addition (0.1%-2.0%,in mass, the same hereinafter),slurry solid content (49.0%-61.9%)and firing temperature (1 300-1 500 ℃)on properties of porous Al2 O3 ceramics were researched.The results show that PG modified the α-Al2 O3 mi-cropowder and well stabilizes the pores;when PG addition is 1.5%and solid content is 58%,the apparent porosity,bulk density and crushing strength of the prepared ceramics fired at 1 500 ℃ are 72%,0.59 g·cm -3 and 12.5 MPa,respectively.

参考文献

[1] 吴海波,袁波,韩建燊,王刚.多孔陶瓷材料的制备研究进展[J].耐火材料,2012(03):230-235.
[2] 曹贺辉,王刚,袁波,韩建燊,董宾宾.泡沫注凝法制备刚玉-莫来石多孔陶瓷[J].耐火材料,2013(05):334-337.
[3] 徐鲲濠,孙阳,黄勇,孙加林.叔丁醇基凝胶注模成型制备氧化铝多孔陶瓷[J].耐火材料,2011(02):93-95,99.
[4] Gonzenbach U T;Gauckler L J;Studart A R et al.Ulstrastable parti-cle-stabilized forms[J].Angew Chen Int Ed,2006,45(21):3526-3530.
[5] Urs T. Gonzenbach;Andre R. Studart;Elena Tervoort .Macroporous Ceramics from Particle-Stabilized Wet Foams[J].Journal of the American Ceramic Society,2007(1):16-22.
[6] Pugh R J;Bergstrom L.Surface and colloid chemistry in advanced ce-ramic processing[M].New York:MarcellDekkler Inc,1994:193-196.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%