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采用电弧离子镀技术在不锈钢基体表面制备了CrNx薄膜,并采用场发射扫描电镜、X射线衍射仪、显微硬度仪、球-盘式摩擦磨损试验机等手段对在不同偏压下沉积的CrNx薄膜的表面形貌、相结构、显微硬度和摩擦学性能进行考察.结果表明:随着偏压的增加, CrNx薄膜沉积率下降,厚度降低,CrNx薄膜表面颗粒逐渐变少,表面粗糙度降低,结晶度增大,晶粒尺寸增加;CrNx薄膜由Cr2N相和CrN相组成,薄膜的择优取向发生较大变化.当偏压为-100V时,CrNx薄膜的表面结构最致密,硬度最高,抗磨损性能最强.

参考文献

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[2] Han ZH.;Tian JW.;Lai QX.;Yu XJ.;Li GY. .Effect of N-2 partial pressure on the microstructure and mechanical properties of magnetron sputtered CrNix films[J].Surface & Coatings Technology,2003(2/3):189-193.
[3] G.A. Zhang;P.X. Yan;P. Wang;Y.M. Chen;J.Y. Zhang .The structure and tribological behaviors of CrN and Cr-Ti-N coatings[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2007(18):7353-7359.
[4] C.-H. Ma;J.-H. Huang;Haydn Chen .Texture evolution of transition-metal nitride thin films by ion beam assisted deposition[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2004(2):184-193.
[5] Lee JW.;Duh JG.;Wang JH. .Mechanical property evaluation of cathodic arc plasma-deposited CrN thin films on Fe-Mn-Al-C alloys[J].Surface & Coatings Technology,2003(2/3):223-230.
[6] Pradhan, SK;Nouveau, C;Vasin, A;Djouadi, MA .Deposition of CrN coatings by PVD methods for mechanical application[J].Surface & Coatings Technology,2005(1/4):141-145.
[7] Logothetidis S;Patsalas P;Sarakinos K;Charitidis C;Metaxa C .The effect of crystal structure and morphology on the optical properties of chromium nitride thin films[J].Surface & Coatings Technology,2004(0):637-641.
[8] Gautier C.;Machet J. .STUDY OF THE GROWTH MECHANISMS OF CHROMIUM NITRIDE FILMS DEPOSITED BY VACUUM ARC EVAPORATION[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1997(1/2):43-52.
[9] Jung MJ.;Nam KH.;Jung YM.;Han JG. .Nucleation and growth behavior of chromium nitride film deposited on various substrates by magnetron sputtering[J].Surface & Coatings Technology,2003(1/3):59-64.
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