目前,钛及钛合金在国民经济和国防工业上的应用越来越广泛,但钛及钛合金也存在一些固有的缺陷,为了进一步提高和改善其使用特性,需要对其进行表面处理.介绍了一些对钛及钛合金行之有效的先进表面处理技术,如化学处理、阳极氧化处理、化学镀及电镀、微弧氧化、电泳沉积和纳米电沉积等,并对其应用加以讨论和评述.这些表面处理方法大大扩展了钛及钛合金的应用领域,促进了钛及钛合金在各行业领域的应用.
Titanium and titanium alloys are excellent candidates in national economics and defense industry. Due to the disadvantages of titanium and its alloys, some surface treatments are adopted to improve the application characteristics.The advanced and effective methods of surface treatment on titanium and its alloys were reviewed and extensively discussed in applications, such as chemical treatment, anodic oxidation treatment, electroless plating and electrodeposition, micro-arc oxidation, electrophoretic deposition, nanoelectrodeposition,etc. The practice results show that the application of surface treatment methods can develop and widen the applied fields of titanium and its alloys.
参考文献
| [1] | Boyer R R .An overview on use of titanium in the aerospace industry[J].J Material Science and Engineering,1996,A213:103-111. |
| [2] | Boyer R R .Titanium for aerospace:rationale and applications[J].Advanced Performance Materials,1995,2(04):349-368. |
| [3] | 彭艳萍.军用新材料的应用现状及发展趋势（待续）[J].材料导报,2000(01):13-16. |
| [4] | 付艳艳,宋月清,惠松骁,米绪军.航空用钛合金的研究与应用进展[J].稀有金属,2006(06):850-856. |
| [5] | Shibuya Y;Sato M;Sato J et al.Titanium and titanium alloy member or surface treatment methods[P].U S Pat:6 221 173,2001-04-24. |
| [6] | Mushiake M;Asano K;Miyamura N .Surface treatment method for titanium or titanium alloys[P].U S Pat:5 051 140,1991-09-24. |
| [7] | Hohman A E;Lively G W .Surface treatment of titanium and titanium alloys[P].U S Pat:3 891 456,1975-06-24. |
| [8] | 邓姝皓,易丹青,林双平,周玲伶.钛的直流阳极氧化工艺研究[J].电镀与精饰,2006(05):15-20. |
| [9] | Judy G;Muraleedharan P;George P et al.Investigation of the antibacterial properties of an anodized titanium alloys[J].Trends Biometer Artif Organs,2003,17(01):13-18. |
| [10] | H. Habazaki;M. Uozumi;H. Konno;K. Shimizu;P. Skeldon;G.E. Thompson .Crystallization of anodic titania on titanium and its alloys[J].Corrosion Science,2003(9):2063-2073. |
| [11] | Shoemaker R H.New chemical surface treatment for processing titanium[A].Los Angeles,Calif,United States:SEA International Press,1973:16-18. |
| [12] | 杨哲龙;张景双;屠振密 等.钛及其合金阳极氧化着色工艺研究[J].材料保护,1992,25(07):196-199. |
| [13] | Aladjem A .Review Anodic of titanium and its alloys[J].Journal of Materials Science,1973,8:688-704. |
| [14] | Song H J;Kim M K;Jung G C et al.Surface treatment of titanium and its alloys[J].Surface and Coatings Technology,2007,201:8 738-8 745. |
| [15] | 赵树萍;吕双坤;郝文杰.钛合金及其表面处理[M].哈尔滨:哈尔滨工业大学出版社,2003:183-190. |
| [16] | A. L. Yerokhin;X. Nie;A. Leyland;A. Matthews;S. J. Dowey .Plasma electrolysis for surface engineering[J].Surface & Coatings Technology,1999(2/3):73-93. |
| [17] | Tang G X;Zhang R J;Yan Y N et al.Preparation of porous anatase titania film[J].Materials Letters,2004,58:1 857-1 860. |
| [18] | 王庆良,徐伶俐,葛世荣.钛合金微弧氧化陶瓷层的结构研究[J].中国表面工程,2007(05):11-15,18. |
| [19] | 薛文斌,邓志威,李永良,陈如意,张通和.Ti-6Al-4V在NaAlO2溶液中微弧氧化陶瓷膜的组织结构研究[J].材料科学与工艺,2000(03):41-45. |
| [20] | 姜兆华,吴晓宏,王福平,辛世刚.Na3PO4-Na2B4O7 体系中钛合金微 等离子体氧化陶瓷膜研究[J].稀有金属,2001(02):151-153. |
| [21] | Nie X;Leyland A;Matthews A .Deposition of layered bioceramic hydroxylapatite/TiO_2 coatings on titanium alloys using a hybrid technique of micro-arc oxidation and electrophoresis[J].Surface and Coatings Technology,2000,125:407-414. |
| [22] | 赵中伟,张刚,李洪桂.Preparation of calcium phosphate coating on pure titanium substrate by electrodeposition method[J].中南工业大学学报(英文版),2004(02):147-151. |
| [23] | Zhang J S;Yang Z L;Tu Z M et al.A new process of electroplating on titanium and titanium alloy for aerospace[J].Transactions of the Institute of Metal Finishing,1996,74(01):25-27. |
| [24] | Yang Z;An M Z;Tu Z M.Study of the process and mechanism of plating directly on titanium and its alloys[J].Plating and Surface Finishing,1997(12):68-71. |
| [25] | 张景双;李萌初;屠振密 等.钛材表面生成"活性膜"的研究[J].电镀与环保,1993,13(05):3-4. |
| [26] | Parkos J J;Lomasney G M;Putnam J W et al.Corrosion resistant surface treatment for structural adhesive bonding to metal[P].U S Pat:6 887 321,2005-05-03. |
| [27] | Zhu L Q;Yang F;Ding N .Corrosion resistance of the electro-galvanized steel treated in a titanium conversion solution[J].Surface and Coatings Technology,2007,201:7 829-7 834. |
| [28] | 李萌初 .钛和钛合金电镀工艺及活化机理的研究[D].哈尔滨:哈尔滨工业大学,1988. |
| [29] | Raqib M .Electroless nickel coating on titanium alloy Ti6Al4V[EB/OL].http://www.finishing.com/475/79.shtml,2008-01-20. |
| [30] | 张天云,张景双,张佩,李宁.铸造钛上直接镀镍工艺的研究[J].电镀与环保,2007(01):5-8. |
| [31] | 杜继红,鞠鹤,蔡天晓,武宏让,康新婷.钛上电镀铜工艺对镀层性能的影响[J].材料保护,2000(12):16-17. |
| [32] | Fornwalt D E;Lomasney G M;Routsis K F et al.Method for electroplating nickel on to titanium alloys[P].U S Pat:4 902 388,1990-02-20. |
| [33] | Bhatia P .Corrosion resistant trivalent chromium phosphated mechanical conversion coatings[P].U S Pat:7 018 486,2006-03-28. |
| [34] | Tang X;Bhatia P;Lomasney G M .Stability additive for trivalent chrome conversion coating bath solutions[P].U S Pat:6 648 986,2003-11-18. |
| [35] | Phelps A W;Sturgill J A;Swartzbaugh J T .Non-toxic corrosion protection conversion coats based on rare earth elements[P].U S Pat:7 407 711,2008-08-05. |
| [36] | Torok F.Non-chrome surface treatment for aerospace application[A].Charlotte,North Carolina,U S:SwRI Press,2004:36-40. |
| [37] | Lin C T .Additive package for in situ phosphatizing paint,paint and method[P].U S Pat:5 322 870,1994-06-21. |
| [38] | 于兴文;李宁;周育红 等.金属表面稀土转化膜[J].材料导报,1998,12(04):24-27. |
| [39] | Luis E P;Zoltan P .Comparative investigation of the adhesion of Ce conversion layers and silane layers to a AA 2024-T3 substrate through mechanical and electrochemical test[J].Materials Research,2007,10(04):399-406. |
| [40] | Yu X W;Cao C N;Yao Z M et al.Corrosion behavior of rare earth metal (REM) conversion coatings on aluminum alloy LY12[J].Materials Science and Engineering A,2003,284(10):56-63. |
| [41] | Campestrini P.;Terryn H.;Hovestad A.;de Wit JHW. .Formation of a cerium-based conversion coating on AA2024: relationship with the microstructure[J].Surface & Coatings Technology,2004(3):365-381. |
| [42] | Fascio V;Wüthrich R;Bleuler H .Spark assisted chemical engraving in the light of electrochemistry[J].Electrochimica Acta,2004,49:3 997-4 003. |
| [43] | Ferreira M G S;Duarte R G;Montemor M F et al.Silanes and rare earth salts as chromate replacers for pre-treatments on galvanised steel[J].Electrochimica Acta,2004,49(17/18):2 927-2 935. |
| [44] | Zhu D .Corrosion protection of metals by silane surface treatment[D].Ohio:University of Cincinnati,2005. |
| [45] | Landolt D;Chauvy P F;Zinger O .Electrochemical micromachining,polishing and surface structuring of metals:fundamental aspects and new developments[J].Electrochimica Acta,2003,48(20-22):3 185-3 201. |
| [46] | 周义.电泳涂装新工艺[M].北京:地质出版社,1999:1-2. |
| [47] | Laxmidhar Besra;Meilin Liu .A review on fundamentals and applications of electrophoretic deposition (EPD)[J].Progress in materials science,2007(26):1-61. |
| [48] | 王伟平.电泳涂装应用和展望[J].电镀与环保,2002(03):25-27. |
| [49] | Claus M;Mark G A.Fabrication of micromechanical structures of titania and titanium with electrophoretic deposition[A].Munich,Germany:Elsevier Science,2001:123-135. |
| [50] | 电泳涂装技术的发展动态[J].汽车工艺与材料,2007(12):1-4,7. |
| [51] | 王绪建.阴极电泳涂装设备的改进及工艺维护[J].电镀与涂饰,2003(01):51-54. |
| [52] | Saber K.;Koch CC.;Fedkiw PS. .Pulse current electrodeposition of nanocrystalline zinc[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2003(1/2):174-181. |
| [53] | Kh.M.S. Youssef;C.C. Koch;P.S. Fedkiw .Improved corrosion behavior of nanocrystalline zinc produced by pulse-current electrodeposition[J].Corrosion Science,2004(1):51-64. |
| [54] | Mishra R;Balasubramaniam R .Effect of nanocrystalline grain size on the electrochemical and corrosion behavior of nickel[J].Corrosion Science,2004,46:3 019-3 029. |
| [55] | 屠振密.电沉积纳米晶材料技术[M].北京:国防工业出版社,2008:60-140. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%