欢迎登录材料期刊网

材料期刊网

高级检索

采用交流阻抗法、断路电位衰退法、循环伏安法等研究了铝基电镀铅-锡合金轻型板栅在硫酸溶液中的电化学行为及其氧化膜的性质,以阐明元素锡对电镀轻型板栅电化学性能的影响.实验结果表明,在铅镀层中添加少量的锡可显著降低铅合金镀层的阳极膜阻抗,促进氧化膜的生长,有利于PbO转变为PbO1+x.

参考文献

[1] Pavlov D;Papazov G;Monahov B .Strap grid tubular plate--a new positive plate for lead-acid batteries:Processes of residual sulphation of the positive plate[J].Journal of Power Sources,2003,113:255-270.
[2] Pavlov D;Monakhov B;Maja M et al.Mechanism of Action of Sn on the Passivation Phenomena in the Lead-Acid Battery Positive Plate (Sn-Free Effect)[J].Journal of the Electrochemical Society,1989,136(17):27-33.
[3] Pavlov D .Effect of corrosion layer on phenomena that cause premature capacity loss in lead/acid batteries[J].Journal of Power Sources,1994,48:179-193.
[4] Yonglang Guo .A New Potential-pH Diagram for an Anodic Film on Pb in H2SO4[J].Journal of the Electrochemical Society,1992,139:2114-2120.
[5] Dimitrov M.K;Pavlov D.Location of the phenomena of premature capacity loss during cycling of lead/acid batteries with lead grids[J].Journal of Power Sources,1993(46):203-210.
[6] D. Pavlov .A theory of the grid/positive active-mass (PAM) interface and possible methods to improve PAM utilization and cycle life of lead/acid batteries[J].Journal of Power Sources,1995(1):9-21.
[7] Pavlov D;Ruevski S;Naidenov V.Influence of temperature,current and number of cycles on the efficiency of the closed oxygen cycle in VRLA batteries[J].Journal of Power Sources,2000(85):164-171.
[8] Slavkov D;Haran B S;Popov B N.Effect of Sn and Ca doping on the corrosion of Pb anodes in lead acid batteries[J].Journal of Power Sources,2002(112):199-208.
[9] 柳厚田,梁海河,杨炯,周伟舫.铅锡合金在硫酸溶液中生长阳极Pb(Ⅱ)氧化物膜的机理[J].高等学校化学学报,2002(01):116-120.
[10] Pavlov D;Rogachev T.Dependence of the phase composition of the anodic layer on oxygen evolution and anodic corrosion of lead electrode in lead dioxide potential region[J].Electrochimica Acta,1978(23):1237-1242l.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%