通过柠檬酸络合法合成B-Er共掺杂BiVO4,采用X-射线衍射和扫描电子显微镜表征合成材料的物相、形貌.同时考察溶液的初始浓度、pH、催化剂投加量以及光照强度等因素在可见光的照射下对金橙Ⅱ光催化降解的影响.实验结果表明,在金橙Ⅱ水溶液中,初始质量浓度为15mg/L、pH =3、催化剂投加量为0.015 g、光照距离14cm,B-Er共掺杂BiVO4对金橙Ⅱ有较好的光催化活性,t为50 min后,降解率可达90%以上.
参考文献
[1] | Huifang Wu;Shihe Wang .Impacts of operating parameters on oxidation-reduction potential and pretreatment efficacy in the pretreatment of printing and dyeing wastewater by Fenton process[J].Journal of hazardous materials,2012(Dec.):86-94. |
[2] | Aandan S;Ashokkumar M .Sonoehemical synthesis of AuTiO2,nanopartieles for the sonophotoeatalytic,degradation of organic pollutants in aqueous environment[J].Uitrason Sonoehem,2009,16(03):316-320. |
[3] | Ying Zhou;Kathrin Vuille;Andre Heel .An inorganic hydrothermal route to photocatalytically active bismuth vanadate[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2010(1):140-148. |
[4] | Fan Hai-mei;Wang De-jun;Wang Ling-ling et al.Hydro thermal Synthesis and Photoelectric Properties of BiVO4 with Different Morphologies[J].An Efficient VisibleLight Photocatalyst ApplSurf Sci,2011,257:7758-7762. |
[5] | 杨世迎,邵雪停,韩强,王平,王静.活性炭/过一硫酸盐降解水中金橙Ⅱ:活性炭的循环利用[J].环境化学,2012(05):692-696. |
[6] | 李国亭,曲久辉,张西旺,刘会娟,李静,雷鹏举.光助电催化降解偶氮染料酸性橙Ⅱ的降解过程研究[J].环境科学学报,2006(10):1618-1623. |
[7] | Min Wang;Haoyan Zheng;Qiong Liu;Chao Niu;Yinsheng Che;Mingyan Dang.High performance B doped BiVO_4 photocatalyst with visible light response by citric acid complex method[J].Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy,2013:74-79. |
[8] | Haiyan Jiang;Xue Meng;Hongxing Dai;Jiguang Deng;Yuxi Liu;Lei Zhang;Zhenxuan Zhao;Ruzhen Zhang .High-performance porous spherical or octapod-like single-crystalline BiVO_4 photocatalysts for the removal of phenol and methylene blue under visible-light illumination[J].Journal of hazardous materials,2012(May 30):92-99. |
[9] | 孔德国,张红美,李晓勤,郑文轩,罗华平.WO3-ZnO复合膜光催化降解亚甲基蓝的研究[J].湖北农业科学,2013(11):2511-2514. |
[10] | Wang Zhen;Wang Yi-ping;Marta Vivar et al.Photovoltaic and photocatalytic performance study of SOLWAT system for the degradation of methylene Blue[J].Acid Red 26 and 4-Chlorophenol Applied Energy,2014,120:1-10. |
[11] | 郑克伟,姜旭东.光催化反应影响因素分析[J].水利科技与经济,2010(12):1354-1355. |
[12] | L. Elsellami;F. Vocanson;F. Dappozze .Kinetic of adsorption and of photocatalytic degradation of phenylalanine effect of pH and light intensity[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2010(1/2):142-148. |
[13] | 刘咏,邹文慧,廖洋,操飞,赵仕林.Ce3+电催化降解甲基橙模拟废水的研究[J].中国稀土学报,2011(01):105-111. |
[14] | Akihiko Kudo .Development of photocatalyst materials for water splitting[J].International journal of hydrogen energy,2006(2):197-202. |
[15] | 王敏,王里奥,张文杰,包亮,杨丽丽.FeVO4光催化剂降解甲基橙研究[J].功能材料,2009(02):201-203,207. |
[16] | 王磊,夏璐,鲁栋梁,胡玉平.二氧化钛紫外光催化降解甲基橙废水的动力学研究[J].化学与生物工程,2010(03):27-31. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%