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在ZTM15(2Y)中加入Al2O3粒子,可以改善材料的微观结构,使ZTM15(2Y)材料的室温力学性能提高。尤其是材料的断裂韧性,由4.0MPa*m1/2增至7.8MPa*m1/2,其主要贡献源于微裂纹增韧。但由于Al2O3粒子的引入,增加了ZTM15(2Y)基体中微裂纹的密度,所以不能有效抑制ZTM15(2Y)材料低温时效处理力学性能下降现象,相反,将加速材料力学性能的退化。

A microstructure with a narrow ZrO2 grain size distribution in the fine mullite grain matrix was obtained by the addition of 5vol%~10vol%Al2O3 particles.The effect of Al2O3 particles on the low tempe-rature ageing of ZTM15(2Y)/Al2O3 composites was studied. The result shows that compared with ZTM15(2Y), the room temperature mechanical properties of ZTM15(2Y)/Al2O3 composites, especially the toughness, are remarkably improved, and toughness could reach 7.8MPa*m1/2. The microcraking is the dominant toughening mechanism. The addition of Al2O3 particles could not inhibit the degradation behavior of ZTM15(2Y) because of the increase of microcraks, on the contrary, enhanced t-m transformation during ageing.

参考文献

[1] 蔡舒 .ZTM材料中低温时效处理及对材料力学性能的影响[D].天津:天津大学,2000.
[2] J M Rincon;T R Dinger;G Thomds et al.Microstructure of mullite/ZrO2 and mullite/Al2O3 tough ceramic composites[J].Acta Metallurgy,1987(35):1175-1179.
[3] M Yoshimura;T Hiufa;S Somiya .Residual stresses and microcraking inducing by thermal contraction homogeneity[J].Journal of the American Ceramic Society,1986,69:583-4.
[4] H Schubert;M Yoshimurs;O Rokakuho.In Zirconia Ceramics Vol 7, Eds S Somiys[J].Tokyo,1986:65-81.
[5] G Orange;G Fantozzi .High temperature mechanical properties of reaction-sintered mullite/zirconia and mullite/alumina/zirconia composites[J].Journal of Materials Science,1985,20:2533-2540.
[6] 李廷凯;沈志坚;丁子上 .ZrO2-Al2O3系陶瓷复合材料力学性质[J].硅酸盐学报,1990(18):39.
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