溶胶-凝胶法制备纳米PZT粉体及结构表征

材料工程, 2006, (3): 52-59. doi: 10.3969/j.issn.1001-4381.2006.03.014

溶胶-凝胶法制备纳米PZT粉体及结构表征

刘红梅 ^1, , 张德庆 ^2, , 林海波 ^3, , 张亮 ^4, , 刘海涛 ^5, , 邱成军 ^6, , 曹茂盛 ^7,

1.哈尔滨工程大学,材料科学与工程系,哈尔滨,150001;黑龙江大学,集成电路重点实验室,哈尔滨,150080

2.哈尔滨工程大学,材料科学与工程系,哈尔滨,150001

3.北京理工大学,材料科学与工程学院,北京,100081

4.北京理工大学,材料科学与工程学院,北京,100081

5.哈尔滨工程大学,材料科学与工程系,哈尔滨,150001

6.哈尔滨工程大学,材料科学与工程系,哈尔滨,150001;黑龙江大学,集成电路重点实验室,哈尔滨,150080

7.哈尔滨工程大学,材料科学与工程系,哈尔滨,150001;北京理工大学,材料科学与工程学院,北京,100081

基金项目: 国家科技攻关项目(2002AA305509) 海军装备攻关项目(401050301) 黑龙江省科技攻关项目(GB02A302)

关键词：溶胶-凝胶 , 乙二醇 , 锆钛酸铅 , 纳米粉体

Synthesis of PZT Nano-crystalline Powder by Sol-gel Method and Structure Characterization

采用改进的溶胶-凝胶法,以乙二醇为溶剂,硝酸锆为锆源,制备了纳米Pb(Zr0.52Ti0.48)O3粉体.通过溶胶的红外光谱分析给出了溶胶、凝胶形成的机理.通过IR,TG-DTA,XRD,SEM,TEM分析对PZT纳米晶的生长过程及性能进行了表征.实验证明:在650℃热处理2h,获得较完整钙钛矿型PZT,粒径约为50～100nm.

参考文献

[1]	Sung-Gap Lee;Young-Hie Lee .Dielectric properties of sol-gel derived PZT(40-60)/PZT(60/40) heterolayered thin films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1999(12):244-248.
[2]	Gene H. Haertling .Ferroelectric ceramics: history and technology[J].Journal of the American Ceramic Society,1999(4):797-818.
[3]	BOLTEN D;BOTTGER U;WASER R .Reversible and irreversible piezoelectric and ferroelectric response in ferroelectric ceramics and thin films[J].Journal of the European Ceramic Society,2004,24(05):725-732.
[4]	SHROUT T R;PAPET P;KIM S;LEE G S .Conventionally prepared submicrometer lead-based perovskite powders by reactive calcinations[J].Journal of the American Ceramic Society,1990,73(07):1862-1867.
[5]	KONG L B;MA J;ZHU W;TAN OK .Highly enhanced sinterability of commercial PZT powders by high-energy ball milling[J].Materials Letters,2000,46(05):274-280.
[6]	Das RN.;Pramanik P.;Pathak A. .Low-temperature preparation of nanocrystalline lead zirconate titanate and lead lanthanum zirconate titanate powders using triethanolamine[J].Journal of the American Ceramic Society,1998(12):3357-3360.
[7]	THOMSON J J .Chemical preparation of PLZT powders from aqueous nitrate solutions[J].American Ceramic Society Bulletin,1974,53(05):421-427.
[8]	RAO K R M;RAO A V P;KOMARNENI S .Reactive PZT precursor powder by coprecipitation[J].Materials Letters,1996,28(04):463-467.
[9]	N.S.Gajbhiye;Sanjay;P. S .Venkataramani .Fabrication of PZT Materials from Nanostructured Powders[J].Progress in Crystal Growth and Characterization of Materials,2002(3):127-131.
[10]	LIU D;ZHANG H;CAI W et al.Synthesis of PZT nanocrystalline powder by a modified sol-gel process using zirconium oxynitrate as zirconium source[J].Materials Chemistry and Physics,1997,51(02):187-189.
[11]	CHENG H;MA J;ZHU B;CUI Y .Reaction mechanisms in the formation of lead zirconate solid solutions under hydrothermal conditions[J].Journal of the American Ceramic Society,1993,76(03):625-628.
[12]	Nathalie Texier;Christian Courtois;Maria Traianidis .Powder process influence on the characteristics of Mn,W,Sb,Ni-doped PZT[J].Journal of the European Ceramic Society,2001(10/11):1499-1502.
[13]	刘大格,蔡伟,张洪喜,吴湘伟,赵连城.以硝酸氧锆为锆源溶胶-凝胶合成PZT纳米晶的研究[J].硅酸盐学报,1998(03):313-318.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网