以粒径约0.5mm的天然鳞片石墨为宿主材料,以高氯酸液为氧化、插层剂,通过简单的酸液浸泡法直接热氧化转化天然鳞片石墨为膨胀石墨.用浓度为72%(质量分数)的高氯酸液在室温下浸泡天然鳞片石墨1~3min.后,在900下膨化,膨胀体积为549mL/g.以该条件制备的膨胀石墨为前驱体通过冷压成型的方法制备柔性石墨,利用材料万能试验机、微欧计、激光热导仪分别测试了该材料的抗拉强度、电阻率、导热率.实验结果表明:抗拉强度(T)、电阻率(ρ)同密度(d)呈线性正相关,其中T=12.1d-7.6,R=0.977;ρ=-3.97d+11.9,R=0.968.热导率同电阻率呈负相关性.
参考文献
[1] | D D L Chung .Review exfoliation of graphite[J].Journal of Materials Science,1987,22:4190-4198. |
[2] | Inagaki, M;Tashiro, R;Washino, Y;Toyoda, M .Exfoliation process of graphite via intercalation compounds with sulfuric acid[J].The journal of physics and chemistry of solids,2004(2/3):133-137. |
[3] | 高林,彭先高.膨胀石墨横断面结构的初步研究[J].新型碳材料,1998(01):61-63. |
[4] | M. Bonnissel;L. Luo;D. Tondeur .Compacted exfoliated natural graphite as heat conduction medium[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(14):2151-2161. |
[5] | M V Savoskin;A P Jaroshenko;O B savsounenko.Direct thermooxidative conversion of graphite to exfoliated graphite.The way to novel technologies[A].,1996:274-275. |
[6] | 陈蔚然.碳素材料工艺基础[M].长沙:湖南大学出版社,1984:8-17. |
[7] | H O Pieson.Handbook of Carbon,Graphite,Diamond,Fullerenes-Properties,Processing,and Application[M].USA:Noyes publication,1993:51-63. |
[8] | Adams PM.;Rellick GS.;Stupian GW.;Katzman HA. .Characterization of high thermal conductivity carbon fibers and a self-reinforced graphite panel[J].Carbon: An International Journal Sponsored by the American Carbon Society,1998(3):233-245. |
[9] | 芦时林,Brian Rand.高导热大直径中间相沥青炭纤维的研制及结构表征[J].新型炭材料,2000(01):1-5. |
[10] | Edie D D;Robinson K;E Fleurot O et al.High thermal conductivity ribbon fibers from naphthalene-based mesophase[J].CARBON,1994,32:1045-1054. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%