欢迎登录材料期刊网

材料期刊网

高级检索

采用Photo DSC(光差热扫描)研究了环氧E-51,二芳基碘鎓盐(CD-1012),光敏剂二异丙基噻唑酮(ITX)组成的阳离子光引发体系的紫外固化动力学.考察了CD-1012和ITX的质量分数、聚合温度、光照强度对其光聚合动力学的影响.利用自加速模型和Arrhenius公式计算了CD-1012/ E-51体系和ITX/CD-1012/ E-51体系的活化能,研究表明光敏剂ITX对CD-1012/ E-51体系具有很好的促进作用.

参考文献

[1] ALLRED R E;HOYT A E;MCELROY P M.UV rigidizable carbon-reinforced isogrid inflatable booms[A].Denver:American Institute of Aeronautics and Astronautics,2002:1-11.
[2] SIMBURGER E J;GIANTS T W;MATSUMOTO J H.Development,dsign,and testing of power sphere multifunctional ultraviolet-rigidizable inflatable structures[A].Norfolk:American Institute of Aeronautics and Astronautics,2003:1-11.
[3] Cho JD;Hong JW .Photo-curing kinetics for the UV-initiated cationic polymerization of a cycloaliphatic diepoxide system photosensitized by thioxanthone[J].European Polymer Journal,2005(2):367-374.
[4] Cho JD;Han ST;Hong JW .A novel in situ relative-conductivity-based technique for monitoring the cure process of UV-curable polymers[J].Polymer Testing,2007(1):71-76.
[5] 孙梦洲,何勇,吴刚强,聂俊.二芳酮-可聚合胺紫外光引发1,6-己二醇二丙烯酸酯聚合的动力学研究[J].感光科学与光化学,2007(01):41-49.
[6] 刘天舒,张宝艳,陈祥宝.3234中温固化环氧树脂体系的固化反应动力学研究[J].航空材料学报,2005(01):45-47,52.
[7] GRASSINO S B;STRUMIA M C;COUVE J M et al.Photoactive systems obtained from methacrylo-urethanes tannic acid-based with potential usage as coating materials:analytic and kinetic acid studies[J].Progress in organic Coatings,1999,37:39-48.
[8] Boey FYC.;Qiang W. .Experimental modeling of the cure kinetics of an epoxy-hexaanhydro-4-methylphthalicanhydride (MHHPA) system[J].Polymer: The International Journal for the Science and Technology of Polymers,2000(6):2081-2094.
[9] SCOTT T F;COOK W D;FORSYTHE J S .Photoinitiation of cationic polymerization by using poly(methy phenyl silane) in combination with addition-fragmentation agents[J].POLYMER,2002,43:5839-5845.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%