用十六烷基三甲基溴化铵和苄基三甲基氯化铵改性膨润土制备了碳柱撑粘土,并对其性能进行了表征.用Cam-bridge S-360型扫描电镜对样品进行了表面形貌对比表征,采用美国ASAP2020型比表面积及孔径测定仪对材料的多孔性质包括比表面积、孔结构、以及孔径分布进行了全面分析,用日本D/MAX-2200PC自动X射线衍射仪对碳柱撑粘土的片层结构做了研究,最后对碳柱撑粘土的热重曲线(TG curve)和差示扫描量热曲线(DSC curve)进行了分析.结果表明:碳柱撑粘土的微观形貌呈针片状,平均孔径较有机粘土小,比表面积增大,碳柱撑粘土的主要结构是碳化的大粒子柱撑而构成的二维孔道,烧结后的有机粘土的热稳定性大大提高.
参考文献
[1] | REGAN BO;GRZEL MA .Low cost high efficiency solav cellbased on dyesensitized colloidal Ti2O films[J].Nature,1991,353:737-740. |
[2] | SNIGIREV A;KOHN V;SNIGIREVAL et al.Compound re-fractive lens for focusing highennryy X-rays[J].Nature,1996,384:49-51. |
[3] | AHENACH COOL P;IMPEN R E N;MOINA R et al.Silica-pillared clay derivarives using aminopropyltriiethoxysilane[J].Journal of Porous Materials,2000,7:475-481. |
[4] | BARRER R M;MCLEOD D M .Activation of mont morillonite byion exchange and sorption complexes of alkylammonium mont morillonite[J].Transactions of the Faraday Society,1995,51(03):1290-1300. |
[5] | DU YIBO;EVANS D G;SUN PENG et al.Advances of resesrch on anionic layeyred materials[J].Chemistry-A European Journal,2000,63(05):20-24. |
[6] | PANG JB;QIU KY;WEI Y .Synthesis of mesoporous poly silica hybrid materials Visa nonsurfactant tempated so-gel process[J].Polymer Science,2000,18(05):469-472. |
[7] | NARAYANAN S;DESHPANDE K .Alumina pillared montmo-rillonite:chracterization and catalysis of tobluene benzylation and aniline ethylation[J].Applied Catalysis A:General,2000,193(1-2):17-27. |
[8] | MORENO S;SUN KOU R;PONCELET G .Influence of preparation variables on the structural,textural and catalytic properties of Al-pil-lared smectites[J].Journal of Physical Chemistry B,1997,101(06):1569-1575. |
[9] | Moreno S.;Kou R.Sun;Molina R. .Al-, Al,Zr-, and Zr-Pillared Montmorillonites and Saponites: Preparation Characterization, and Catalytic Activity in Heptane Hydroconversion[J].Journal of Catalysis,1999(1):174-185. |
[10] | Sychev M.;Kodentsov A.;Vanoers EM.;Vansanten RA.;Debeer VHJS. .CHROMIA- AND CHROMIUM SULFIDE-PILLARED CLAYS - PREPARATION, CHARACTERIZATION, AND CATALYTIC ACTIVITY FOR THIOPHENE HYDRODESULFURIZATION[J].Journal of Catalysis,1997(2):245-254. |
[11] | GUIN G;GIL A;MONTES M et al.Tantalum-pillared montmorl-lonite 1.synthsis and physicochemical characterization[J].Journal of Catalysis,1997,168(01):450-462. |
[12] | LEWIS R M;OTT K C;VAN SANTEN R A .Silica-clay complexes[P].US 4510257,1985-04-09. |
[13] | CHAE H J;NAM IS;HAM S W et al.Physicochemical characterisitics of pillared interlayered clays[J].Catalysis Today,2001,68(01):31-40. |
[14] | YANGRT;BAKSHMSA .Pillared clays as a new class of adsorbents for gas separation[J].AICHE Journal,1991,37(05):679-660. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%