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以NH4Cl为氮源,采用溶胶-凝胶法制备N掺杂纳米TiO2,以4-氯苯酚和TOC降解率为指标,考察灼烧温度、搅拌速度、溶液pH值等因素对N掺杂TiO2可见光活性及动力学方程的影响.结果表明,N掺杂TiO2对4-氯苯酚具有良好的降解作用,在灼烧温度400℃、快速搅拌、pH值为4.6下,4-氯苯酚降解率最大,在可见光辐射6h时达到87%..降解反应符合Langmuir-Hinshelwood动力学方程.

参考文献

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[2] SAKTHIVEL S;KISCH H .Photocatalytic and photoelectrochemical properties of nitrogen-doped titanium dioxide[J].ChemPhysChem:A European Journal of Chemical Physics and Physical Chemistry,2003,4(05):487-490.
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[5] Y. Liu;X. Chen;J. Li;C. Burda .Photocatalytic degradation of azo dyes by nitrogen-doped TiO_2 nanocatalysts[J].Chemosphere,2005(1):11-18.
[6] 於煌,郑旭煦,殷钟意,陶丰,房蓓蓓,侯苛山.纳米N掺杂TiO2的制备及可见光催化活性研究[J].中国化学工程学报(英文版),2007(06):802-807.
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