采用静电纺丝技术和层层组装技术制备了聚电解质/TiO2复合中空纳米纤维.以电纺聚苯乙烯纤维为模板,聚电解质交替吸附在纤维表面,再用有机溶剂溶掉PS纤维模板获得多层聚电解质中空纤维.纤维的平均直径和壁厚能通过模板和吸附层数很好的得到控制.在对比P25 TiO2和TiO2中空纤维对亚甲基蓝的光催化性能实验中,发现TiO2中空纤维具有更好的光催化性能.TiO2/聚电解质复合中空纳米纤维有望应用于光催化,可控药物释放等.
参考文献
[1] | Liu SM.;Gan LM.;Liu LH.;Zhang WD.;Zeng HC. .Synthesis of single-crystalline TiO2 nanotubes[J].Chemistry of Materials,2002(3):1391-1397. |
[2] | ZHANG L;YU J C .A sonoehemical approach to hierarchical porous titania spheres with enhanced photocatalytic activity[J].Chemical Communications,2003,2078:46-51. |
[3] | ZHAN S H;CHEN D R;JIAO X L et al.Long TiOz hollow fihers with mesoporous walls:sol-gel combined electrospun fabrication and photocatalytic properties[J].Journal of Physical Chemistry B,2006,110:11199-11204. |
[4] | HUANG JIN M;ZHANGY Z;KOTAKI.M et al.A review on polymer nanofibers by electrospinning and their applications in nanocomposites[J].Composites Science and Technology,2003,63:222-226. |
[5] | Dan Li;Yuliang Wang;Younan Xia .Electrospinning of Polymeric and Ceramic Nanofibers as Uniaxially Aligned Arrays[J].Nano letters,2003(8):1167-1171. |
[6] | Abidian, MR;Kim, DH;Martin, DC .Conducting-polymer nanotubes for controlled drug release[J].Advanced Materials,2006(4):405-409. |
[7] | ZHANG Y Z;WANG X;FENG Y et al.Coaxial electrospinning of(fluorescein isothiocyanate-conjugated bovine serum albumin)-encapsulated poly(ε-caprolactone)nanofibers for sustained release[J].Biomacromolecules,2006,7:1049-1057. |
[8] | Todd C. Sutherland;Yi-Tao Long;Radu-Ioan Stefureac;Irene Bediako-Amoa;Heinz-Bernhard Kraatz;Jeremy S. Lee .Structure of Peptides Investigated by Nanopore Analysis[J].Nano letters,2004(7):1273-1277. |
[9] | Ignacio G. Loscertales;Antonio Barrero;Manuel Marquez;Ruben Spretz;Raffet Velarde-Ortiz;Gustavo Larsen .Electrically Forced Coaxial Nanojets for One-Step Hollow Nanofiber Design[J].Journal of the American Chemical Society,2004(17):5376-5377. |
[10] | ZHANGY Z;XU X J;HUANGZM et al.Preparation of coreshell structured PCL-r-gelatin bi-component nanofibers by coaxial electrospinning[J].CHEMISTRY OF MATERIALS,2004,16:3406-3410. |
[11] | WANG M;YU J H;KAPLANDL et al.Production of submicron dianleter Silk fibers under benign processing conditions by two-fluid electrospinning[J].Macromolecuhs,2006,39:1102-1107. |
[12] | Ding B;Li CR;Fujita S;Shiratori S .Layer-by-layer self-assembled tubular films containing polyoxometalate on electrospun nanotibers[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2006(0):257-262. |
[13] | DING B;KIM J;KIMURA E et al.Layer-by-layer structured films of TiO2 nanoparticles and poly(acrylic add)on electrospun nanofibres[J].NANOTECHNOLOGY,2004,15:913-917. |
[14] | LI D;XIA Y N .Fabrication of titania nanofibers by electrospinning[J].Nano Letters,2003,3:555-560. |
[15] | Caruso RA.;Greiner A.;Schattka JH. .Titanium dioxide tubes from sol-gel coating of electrospun polymer fibers[J].Advanced Materials,2001(20):1577-0. |
[16] | Chao Pan;Li-Qin Ge;Zhong-Ze Gu .Fabrication of multi-walled carbon nanotube reinforced polyelectrolyte hollow nanofibers by electrospinning[J].Composites science and technology,2007(15/16):3271-3277. |
[17] | M LLER K;QUINN J F;JOHNSTON A P R .Polyelectrolyte funetionalization of electrospun fibers[J].Chemistry of Materials,2006,18:2397-2403. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%