分别采用浸渍一提拉法和液相渗透(LPI)法用SnO2前驱物填充模板得到SnO2/PS复合膜,灼烧去除模板后,成功地制备了三维有序多孔SnO1膜.PS胶粒晶体模板是用乳液聚合法合成的单分散PS微球通过垂直沉积法在55℃组装而成.实验结果显示,由改进的LPI法制备的三维有序多孔膜质量相对较高,面积较大并且无"表皮"覆盖.在灼烧去除模板的过程中孔径有一定的收缩.
参考文献
[1] | FERRERE S;ZABAN A;GREGG B A .Dye sensitization of nanocrystalline tin oxide by perylene derivatives[J].Journal of Physical Chemistry B,1997,101(23):4490-4493. |
[2] | 吕宝堂,赵晖,郑君,邹邦涛,贾兆滨.外连式SnO2导电膜非晶硅太阳电池[J].电源技术,2002(02):89-91. |
[3] | 张谢群,余家国,赵修建,赵丽,刘升卫.二氧化锡薄膜的制备和应用研究进展[J].化学试剂,2003(04):203-206. |
[4] | 赵全明,王广健,李玲玲,蒋栋.二氧化锡膜气敏传感器最新研究成果[J].传感器世界,2002(07):1-6. |
[5] | 越泽廷;姚纲照 .气敏膜的喷涂-热处理法研究[J].仪表技术与传感器,1997,7:10-12. |
[6] | Lee SW.;Chen H.;Tsai PP. .Comparison study of SnO2 thin- and thick-film gas sensors[J].Sensors and Actuators, B. Chemical,2000(1/2):122-127. |
[7] | Yanan Fu;Zhengguo Jin;Zhifeng Liu .Preparation of ordered porous SnO_2 films by dip-drawing method with PS colloid crystal templates[J].Journal of the European Ceramic Society,2007(5):2223-2228. |
[8] | DEKI S;ZLIZUKA S;MIzuHATA M et al.Fabrication of nano-structured materials from aqueous solution by liquid phase deposition[J].Journal of Electroanalytical Chemistry,2005,584:38-43. |
[9] | Minoru MIZUHATA;Yuki KIDA;Shigehito DEKI .Enhancement of Photoluminescence from Eu~(3+) Doped ZrO2 in SnO2 Inverse Opal Structure Prepared by the Liquid Phase Infiltration Method[J].日本セラミックス协会学术论文志,2007(1347):724-728. |
[10] | 刘丽霞 .新型胶粒晶体的组装与修饰[D].中国石油大学(北京),2005. |
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