欢迎登录材料期刊网

材料期刊网

高级检索

运用紫外可见吸收光谱,在水相金溶胶体系中研究了聚乙烯吡咯烷酮(PVP)在金纳米粒子表面的吸附.实验结果表明:PVP吸附在金纳米粒子的表面,使金纳米粒子的特征吸收峰的峰位红移15nm左右且强度下降.根据金溶胶中PVP加入量和特征吸收峰的变化,提出了PVP对溶胶中金纳米粒子的表面包裹经过的过程.

参考文献

[1] Tang XL;Jiang P;Ge GL;Tsuji M;Xie SS;Guo YJ .Poly(N-vinyl-2-pyrrolidone) (PVP)-capped dendritic gold nanoparticles by a one-step hydrothermal route and their high SERS effect[J].Langmuir: The ACS Journal of Surfaces and Colloids,2008(5):1763-1768.
[2] STEPHANIE V;ISABEL P S;JORGE P J et al.Plasmon couling in layer-by-layer assembled gold nanorod films[J].Langmuir,2007,23:4606-4611.
[3] Chil Seong Ah;Yong Ju Yun;Hyung Ju Park;Wan-Joong Kim;Dong Han Ha .Size-Controlled Synthesis of Machinable Single Crystalline Gold Nanoplates[J].Chemistry of Materials,2005(22):5558-5561.
[4] Xiong YJ;Washio I;Chen JY;Cai HG;Li ZY;Xia YN .Poly(vinyl pyrrolidone): A dual functional reductant and stabilizer for the facile synthesis of noble metal nanoplates in aqueous solutions[J].Langmuir: The ACS Journal of Surfaces and Colloids,2006(20):8563-8570.
[5] Pardinas-Blanco I;Hoppe CE;Pineiro-Redondo Y;Lopez-Quintela MA;Rivas J .Formation of gold branched plates in diluted solutions of poly(vinylpyrrolidone) and their use for the fabrication of near-infrared-absorbing films and coatings[J].Langmuir: The ACS Journal of Surfaces and Colloids,2008(3):983-990.
[6] Hironori Tsunoyama;Hidehiro Sakurai;Yuichi Negishi;Tatsuya Tsukuda .Size-Specific Catalytic Activity of Polymer-Stabilized Gold Nanoclusters for Aerobic Alcohol Oxidation in Water[J].Journal of the American Chemical Society,2005(26):9374-9375.
[7] FRENS G .Regulation of the particle size in monodisperse gold suspensions[J].Nature,1973,241(105):20-22.
[8] 胡梦 .核壳结构微粒的制备与表征[D].浙江大学,2007.
[9] KREIBIG U;VOLLMER M.Optical properties of met al clusters[M].Berlin:springer-verlag,1995
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%