采用真空浸渗的方法,将棕榈酸和十六醇的低共熔物(PA-HD)与膨胀珍珠岩(EP)结合,制备一种新型定形相变材料(PA-HD/EP).环境扫描电子显微镜测试显示相变材料PA-HD进入到珍珠岩的孔道结构中.棕榈酸和十六醇的低共熔物在膨胀珍珠岩的最佳浸渗量为58.0%(质量分数,下同),在此浸渗量下,即使是没有进行包覆,PA-HD也不会在发生相变时从EP中渗漏.差示扫描量热仪测试获得PA-HD/EP的熔点为41.49℃,相变焓值为122.9J/g.通过在PA-HD/EP中添加10%石墨,改善材料的导热性能.该复合相变材料可以很好地与普通建筑材料进行结合,进一步制备成具有温度调节功能的建筑材料.
参考文献
[1] | MOHAMMED M F;AMAR M K;SIDDIQUE A K R et al.A review on phase change energy storage:materials and applications[J].Energy Conversion and Management,2004,45(9-10):1597-1615. |
[2] | A. Pasupathy;R. Velraj;R.V. Seeniraj .Phase change material-based building architecture for thermal management in residential and commercial establishments[J].Renewable & sustainable energy reviews,2008(1):39-64. |
[3] | 马保国,蹇守卫,金磊,穆松,张琴.无机/相变定型储能材料的制备研究进展[J].材料导报,2008(12):36-39,43. |
[4] | Y.P. Zhang;K.P. Lin;R. Yang;H.F. Di;Y. Jiang .Preparation, thermal performance and application of shape-stabilized PCM in energy efficient buildings[J].Energy and buildings,2006(10):1262-1269. |
[5] | Ahmet Sari .Eutectic mixtures of some fatty acids for latent heat storage: Thermal properties and thermal reliability with respect to thermal cycling[J].Energy Conversion & Management,2006(9/10):1207-1221. |
[6] | 张东,周剑敏,吴科如,李宗津.颗粒型相变储能复合材料[J].复合材料学报,2004(05):103-109. |
[7] | SCARPA F;MILANO G .The role of adsorption and phase change phenomena in the thermophysical characterization of moist porous materials[J].International Journal of Theoretical Physics,2002,23(04):1033-1046. |
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