采用悬浮聚合制备了醋酸乙烯酯-三烯丙基异氰酸酯共聚物大孔树脂颗粒,研究了交联剂和致孔剂用量对大孔树脂颗粒密度、孔体积和孔隙率的影响,结果表明:树脂的孔体积和孔隙率随致孔剂的用量及树脂颗粒直径的增加而增大.空气声吸收性能测试结果表明:在PU/EP共混物基体中加入大孔树脂颗粒能增强其吸声效果;水声性能测试表明:在PU/EP共混物基体中加入10%(质量分数)的大孔树脂颗粒能显著提高其吸声系数,平均吸声系数由0.13增加到0.65,峰值由0.29增加到0.94.
参考文献
[1] | Ng YH;Hong L .Acoustic attenuation characteristics of surface-modified polymeric porous microspheres[J].Journal of Applied Polymer Science,2006(2):1202-1212. |
[2] | BAIRD A M;KERR F H .Wave propagation in a viscoelastic medium containing fluid-filled microspheres[J].Journal of The Acoustical Society of America,1999,105(03):1527-1538. |
[3] | Zhou H;Li B;Huang GS .Sound absorption characteristics of polymer microparticles[J].Journal of Applied Polymer Science,2006(4):2675-2679. |
[4] | 刘吉轩;陈天宁;张升陛 等.高分子颗粒孔隙结构材料的吸声特性研究[J].应用声学,1996,15(04):38-42. |
[5] | 周洪,李波,黄光速.高分子微粒吸声材料的声学特性[J].高分子材料科学与工程,2004(03):190-193. |
[6] | 晏欣,姚树人.P(VA-co-DBM)/PVA乳胶IPN阻尼材料的合成及动态力学性能[J].功能高分子学报,2001(03):315-318. |
[7] | Ying Wan;Wenqiang Huang;Zheng Wang;X.X.Zhu .Preparation and characterization of high loading porous crosslinked poly(vinyl alcohol) resins[J].Polymer: The International Journal for the Science and Technology of Polymers,2004(1):71-77. |
[8] | HARTMANN B;LEE G F;LEE J D et al.Sound absorption height and width limits for polymer relaxation[J].Journal of The Acoustical Society of America,1997,101(04):2009-2011. |
[9] | KERWIN E M .Damping of flexural waves by a constrained viscoelastic layer[J].Journal of The Acoustical Society of America,1959,31(07):952-962. |
[10] | 于晓强,李耀先,王静媛,李峰,孟岩,汤心颐,孙家锺.聚合物材料的吸音系数-温度-频率三元关系的研究[J].高等学校化学学报,2000(01):144-147. |
[11] | GAUNAURD G C .One-dimensional model of acoustic absorption in a viscoelastic medium containing short cylindrical cavities[J].Journal of The Acoustical Society of America,1977,62(02):298-307. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%