依据天然气减阻剂减阻机理及缓释作用机理,合成了一种新型天然气减阻剂硬脂酸咪唑啉,探讨了其在钢铁表面吸附成膜的机理,并在天然气减阻剂室内评价系统上进行了减阻率测试;通过电化学分析及扫描电子显微镜对其在钢铁表面的成膜性能进行研究.结果表明:硬脂酸咪唑啉能够牢固吸附在输气管道内表面上形成一层光滑的弹性分子膜,显著改善了输气管道内表面的粗糙度,在硬脂酸咪唑啉浓度为8g/L、成膜时间为1h时,测得最大减阻率8.7%,为天然气减阻剂的工业化开发奠定了基础.
参考文献
[1] | 张静.天然气与中国能源发展前景[J].中国石油和化工经济分析,2007(12):20-24. |
[2] | 宋玉春.2007年世界油气管道工程建设总览[J].中国石油和化工 |
[3] | 阎光灿.世界长输天然气管道综述[J].天然气与石油,2000(03):9-19. |
[4] | 吴长春,张孔明.天然气的运输方式及其特点[J].油气储运,2003(09):39-43. |
[5] | 王功礼,王莉.油气管道技术现状与发展趋势[J].石油规划设计,2004(04):1-7. |
[6] | 阎光灿,冯亚利,吴邦辉.世界天然气输送管网系统(续完)[J].天然气与石油,1999(01):58-63. |
[7] | 阎光灿,冯亚利,吴邦辉.世界天然气输送管网系统(待续)[J].天然气与石油,1998(04):57. |
[8] | 吴玉国,陈保东.输气管线摩阻系数的影响因素以及减阻的主要方法[J].管道技术与设备,2003(05):1-3. |
[9] | SLETFJERDING E;GUDMUNDSSON J S.Friction factor in gas pipelines in the North Sea[A].Texas USA:SPE,2000:459-467. |
[10] | 林竹,刘本华,刘书国.输气管道减阻涂料现状及发展趋势[J].上海涂料,2004(01):16-18. |
[11] | 吴玉国;陈保东 .输气管线摩阻公式评价[J].油气储运,2003,22(01):23-28. |
[12] | 沈善策.输气管道采用内壁覆盖层时的工艺设计问题[J].油气储运,2000(07):19. |
[13] | KUT S .High performance coatings for the oil and gas industry internal and external liquid coatings for pipelines,corrosion in the oil and gas industry[D].Kosice,Czechoslovakia:Technical University,1989. |
[14] | 钱成文,刘广文,王武,刘春林.天然气管道的内涂层减阻技术[J].油气储运,2001(03):1-5,6. |
[15] | 胡士信;陈向新.天然气管道减阻内涂技术[M].北京:化学工业出版社,2003 |
[16] | 林竹,张丽萍,袁中立,秦延龙.减阻型涂料在天然气管道中的应用[J].焊管,2002(06):1-4. |
[17] | 刘雯,钱成文.输气管道内涂层用涂料[J].油气储运,2001(02):13-15,19. |
[18] | FRANK E L .Drag Reduction Method for Gas Pipelines[P].US Patent:4958653,1990-07-26. |
[19] | LI Ying-Hsiao .Drag Reduction Method For Gas Pipelines[P].US Patent:5020561,1991-06-04. |
[20] | LI Y H;CHESNUT G R;RICHMOND R D et al.Laboratory tests and field implementation of gas-drag-reduction chemicals[J].SPE Production and Facilities,1998,13(01):53-58. |
[21] | CHEN H J;KOUBA G E;MICHAEL S .DRA for gas pipelining successful in gulf of mexico trial[J].Oil & Gas Journal,2000,98(23):54-58. |
[22] | S. Ramachandran;V. Jovancicevic .Molecular modeling of the inhibition of mild steel carbon dioxide corrosion by imidazolines[J].Corrosion: The Journal of Science and Engineering,1999(3):259-267. |
[23] | J. Cruz;R. Martinez;J. Genesca;E. Garcia-Ochoa .Experimental and theoretical study of 1-(2-ethylamino)-2-methylimidazoline as an inhibitor of carbon steel corrosion in acid media[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2004(1):111-121. |
[24] | ZHENG J S;ZHAO J G .Control of corrosion by inhibitors in drilling muds containing high concentration of H2S[J].Corrosion,1993,49(02):170-174. |
[25] | MARTIN J A .The existence of imidazoline corrosion inhibitors[J].Corrosion,1985,41(05):281-287. |
[26] | 吕彤,李凡,郭晓红.咪唑啉柔软剂中间体的合成研究[J].天津纺织工学院学报,1999(01):30-32. |
[27] | 王慧龙,韩秀丽,郑家.高级脂肪酰胺基烷基咪唑啉的合成及缓蚀研究[J].郑州工业大学学报(自然科学版),2001(03):62-64. |
[28] | 刘瑞斌,王慧龙,辛剑,江平.高级脂肪酰胺基烷基咪唑啉合成工艺条件的研究[J].广东化工,2004(02):7-8. |
[29] | JOVANCICEV V .Inhibition of Co2 corrosion of mild steel by imidazolines and their precursors[J].NACE Corrosion,1999,55(05):449-455. |
[30] | 王大喜,俞英.新型咪唑啉化合物的合成及缓蚀性能测试[J].石油大学学报(自然科学版),2000(06):52-54. |
[31] | L. Zhao;H. K. Teng;Y. S. Yang;X. Tan .Corrosion inhibition approach of oil production systems in offshore oilfields[J].Materials and Corrosion,2004(9):684-688. |
[32] | WANG Da-xi;LI Shu-yuan;YU Ying .Theoretical and experimental studies of structure and inhibition efficiency of imidazoline derivatives[J].Corrosion Science,1999,41(10):1911-1919. |
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