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采用熔盐法在不同温度下制备出层状浓度梯度型LiNi1-x-yCoxMnyO2正极材料.经XRD,SEM实验分析表明:材料具有典型的a-NaFeO2层状结构,粒径在200~400nm之间.在2.75~4.5V充放电电压范围内测试,800℃得到的材料首次放电比容量为166.8mAh/g,保持率为99%;同时,在2C电流以内充放电,该材料表现出较稳定的倍率性能.

参考文献

[1] LID C;KATO Y;KOBAYAKAWA K et al.Preparation and electrochemical characteristics of LiNi1/3 Mn1/3 Co1/3O2 coated with metal oxides coating[J].Journal of Power Sources,2006,160:1342-1348.
[2] KIM G H;MYUNG S T;KIM H S et al.Synthesis of spherical Li[Ni(1/3-z)Co(1/3-z)Mn(1/3 z)Mgz]O2 as positive electrode material for lithium-ion battery[J].Electrochimica Acta,2006,51:2447-2453.
[3] Li Qin Wang;Li Fang Jiao;Hua Tang Yuan .Synthesis and electrochemical properties of Mo-doped Li[Ni_(1/3)Mn_(1/3)Co_(1/3)]O_2 cathode materials for Li-ion battery[J].Journal of Power Sources,2006(2):1367-1372.
[4] Sun, YK;Myung, ST;Kim, MH;Prakash, J;Amine, K .Synthesis and characterization of Li[(Ni0.8Co0.1Mn0.1)(0.8)(Ni0.5Mn0.5)(0.2)]O-2 with the microscale core-shell structure as the positive electrode material for lithium batteries[J].Journal of the American Chemical Society,2005(38):13411-13418.
[5] Yang-Kook Sun;Seung-Taek Myung;Byung-Chun Park .High-energy cathode material for long-life and safe lithium batteries[J].Nature materials,2009(4):320-324.
[6] H.F. Xiang;H. Wang;C.H. Chen;X.W. Ge;S. Guo;J.H. Sun;W.Q. Hu .Thermal stability of LiPF_6-based electrolyte and effect of contact with various delithiated cathodes of Li-ion batteries[J].Journal of Power Sources,2009(2):575-581.
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