本文概述了目前高介电聚合物基复合材料的主要问题,论述了铁电陶瓷、导电颗粒(金属粒子、石墨、碳纳米管)改性高介电复合材料的国内外研究进展；重点介绍了酞菁铜、聚苯胺改性全有机高介电复合材料,探讨了存在的主要问题,并指出提高介电常数、储能密度,减小介电损耗,降低制备成本是未来发展的方向.
参考文献
| [1] | KINGON A I;MARIA J P;STREIFFER S K .Alternative die lectrics to silicon dioxide for memory and logic devices[J].Nature,2000,406(6799):1032-1038. |
| [2] | Junjun Li;Jason Claude;Luis Enrique Norena-Franco .Electrical Energy Storage in Ferroelectric Polymer Nanocomposites Containing Surface-Functionalized BaTiO3 Nanoparticles[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(20):6304-6306. |
| [3] | JUNG H M;KANG J H;YANG S Y et al.Barium titanate nanoparticles with diblock copolymer shiclding layers for high-energy density nanocomposites[J].Chemistry of Materials,2010,22(02):450-456. |
| [4] | Zhang YH;Ke SM;Huang HT;Zhao LH;Yu L;Chan HLW .Dielectric relaxation in polyimide nanofoamed films with low dielectric constant[J].Applied physics letters,2008(5):52910-1-52910-3-0. |
| [5] | ZHANG Y H;SU Q;YU L et al.Study on the dielectric properties of hybrid and porous polyimide-silica films[J].Current Advances in Materials and Processes,2008,47-50:973-976. |
| [6] | ZHANG Y H;SU Q;YU L et al.Preparation and characterization of functional geopolymer[J].Current Advances in Materials and Processes,2008,47-50:987-990. |
| [7] | ZHANG Q M;BHARTI VIVEK;ZHAO X .Giant electrostriction and relaxor ferroelectric behavior in electron-irradiated poly (vinylidene fluoride-trifluoroethylene) copolymer[J].Science,1998,280(5372):2101-2104. |
| [8] | 王晔 .高介电常数高分子复合材料研究[D].南京航空航天大学,2008. |
| [9] | Chu BJ;Zhou X;Ren KL;Neese B;Lin MR;Wang Q;Bauer F;Zhang QM .A dielectric polymer with high electric energy density and fast discharge speed[J].Science,2006(5785):334-336. |
| [10] | 党智敏 .高介电无机/有机复合材料的研究[D].北京:清华大学,2003. |
| [11] | Reversible phase transition and structure memory effect of metastable phase in electron-irradiated poly(vinylidene-fluoride-trifluoroethyline) copolymers[J].Applied physics letters,2003(13):2136-2138. |
| [12] | Milind Arbatti;Xiaobing Shan;Zhongyang Cheng .Ceramic-Polymer Composites with High Dielectric Constant[J].Advanced Materials,2007(10):1369-1372. |
| [13] | Tokura Y.;Kuwahara H.;Asamitsu A.;Moritomo Y.;Kasai M.;Tomioka Y. .ORIGINS OF COLOSSAL MAGNETORESISTANCE IN PEROVSKITE-TYPE MANGANESE OXIDES[J].Journal of Applied Physics,1996(8 Pt.2a):5288-5291. |
| [14] | Sung-Dong Cho;Joo-Yeon Lee;Jin-Gul Hyun .Study on epoxy/BaTiO_3 composite embedded capacitor films (ECFs) for organic substrate applications[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2004(3):233-239. |
| [15] | 杨晓军,杨志民,毛昌辉,杜军.高介电常数EP/BT复合材料介电性能的研究[J].化工新型材料,2006(12):27-30. |
| [16] | 陈章,马寒冰,杨宁宁,张丽娟,蔡勇.BaTiO3/环氧高介电常数复合材料[J].材料科学与工程学报,2007(06):914-916. |
| [17] | 陈惠玲,余萍,肖定全.钛酸钡/环氧介电复合材料制备技术的研究[J].功能材料,2008(03):367-370. |
| [18] | 刘卫东,刘小芬,朱宝库,谢曙辉,徐志康.聚酰亚胺/钛酸钡复合膜介电性能及其影响因素的研究[J].功能材料,2007(07):1106-1109. |
| [19] | Zhi-Min Dang;You-Qin Lin;Hai-Ping Xu;Chang-Yong Shi;Sheng-Tao Li;Jinbo Bai .Fabrication and Dielectric Characterization of Advanced BaTio_3/Polyimide Nanocomposite Films with High Thermal Stability[J].Advanced functional materials,2008(10):1509-1517. |
| [20] | VREJOIU I;PEDARNIG J D;B(A)UERLE D .Giant dielectric permittivity and electromechanical strain in thin film materials produced hy pulsed-laser deposition[J].Applied Physics Letters,2003,83(11):2130-2132. |
| [21] | Wen Xiang Yuan;Sui Kong Hark;Wai Ning Mei .Effective synthesis to fabricate a giant dielectric-constant material CaCu3Ti4O_(12) via solid state reactions[J].Journal of Ceramic Processing Research. (Text in English),2009(5):696-699. |
| [22] | Loic Marchin;Sophie Guillemet-Fritsch;Bernard Durand .Grain Growth-Controlled Giant Permittivity in Soft Chemistry CaCu_3Ti_4O_(12) Ceramics[J].Journal of the American Ceramic Society,2008(2):485-489. |
| [23] | Rainer Schmidt;Derek C. Sinclair .Anomalous Increase of Dielectric Permittivity in Sr-Doped CCTO Ceramics Ca_(1-x)Sr_xCu3Ti_4O_(12)(0 ≤x ≤ 0.2)[J].Chemistry of Materials: A Publication of the American Chemistry Society,2010(1):6-8. |
| [24] | DANG Z M;ZHOU T;YAO S H et al.Advanced calcium copper titanate/polyimide functional hybrid films with high dielectric permittivity[J].Advanced Materials,2009,21(20):20772082. |
| [25] | Pecharroman C.;Moya JS. .Experimental evidence of a giant capacitance in insulator-conductor composites at the percolation threshold[J].Advanced Materials,2000(4):294-297. |
| [26] | RAO Y;WONG C P.Ultra high dielectric constant epoxy silver composite for embedded capacitor application[A].New York:USA:IEEE,2002:920-923. |
| [27] | Xingyi Huang;Pingkai Jiang;Liyuan Xie .Ferroelectric polymer/silver nanocomposites with high dielectric constant and high thermal conductivity[J].Applied physics letters,2009(24):242901-1-242901-3. |
| [28] | Zhi-Ming Dang;Yuan-Hua Lin;Ce-Wen Nan .Novel Ferroelectric Polymer Composites with High Dielectric Constants[J].Advanced Materials,2003(19):1625-1629. |
| [29] | Yun-Jia Li;Man Xu;Jun-Qiang Feng;Zhi-Min Dang .Dielectric behavior of a metal-polymer composite with low percolation threshold[J].Applied physics letters,2006(7):072902-1-072902-3-0. |
| [30] | Hyung-Woo Choi;Young-Woo Heo;Joon-Hyung Lee .Effects of Ni Particle Size on Dielectric Properties of PMMA-Ni-BaTiO_3 Composites[J].Integrated Ferroelectrics,2007(1):85-93. |
| [31] | Maheswar Panda;V. Srinivas;A. K. Thakur .On the question of percolation threshold in polyvinylidene fluoride/nanocrystalline nickel composites[J].Applied physics letters,2008(13):132905-1-132905-3-0. |
| [32] | Maheswar Panda;V. Srinivas;A. K. Thakur .Surface and interfacial effect of filler particle on electrical properties of polyvinyledene fluoride/nickel composites[J].Applied physics letters,2008(24):242908-1-242908-3-0. |
| [33] | FAN L;KUMASHIRO Y;WONG C P.Integral capacitor dielectrics based on polymer composites with specialty conductive fillers[A].New York:USA:IEEE,2003:167-172. |
| [34] | Qi, L;Lee, BI;Chen, SH;Samuels, WD;Exarhos, GJ .High-dielectric-constant silver-epoxy composites as embedded dielectrics[J].Advanced Materials,2005(14):1777-1780. |
| [35] | Lu JX;Moon KS;Xu JW;Wong CP .Synthesis and dielectric properties of novel high-K polymer composites containing in-situ formed silver nanoparticles for embedded capacitor applications[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2006(16):1543-1548. |
| [36] | Yang Shen;Yuanhua Lin;Ming Li;Ce-Wen Nan .High Dielectric Performance of Polymer Composite Films Induced by a Percolating Interparticle Barrier Layer[J].Advanced Materials,2007(10):1418-1422. |
| [37] | Shen Y;Lin YH;Nan CW .Interfacial effect on dielectric properties of polymer nanocomposites filled with core/shell-structured particles[J].Advanced functional materials,2007(14):2405-2410. |
| [38] | XU J W;WONG C P .Low-loss percolativc dielectric composite[J].Applied Physics Letters,2005,87(08):082907-1-082907-3. |
| [39] | 张璇,梁国正,晁芬,刘继三,王金合,管兴华.双马来酰亚胺/BA/石墨介电材料的制备及性能研究[J].中国塑料,2007(08):42-46. |
| [40] | PANWAR V;MEHRA R M .Analysis of electrical,dielectric,and electromagnetic interference shiclding behavior of graphite filled high density polyethylene composites[J].Polymer Engineering and Science,2008,48(11):21782187. |
| [41] | Fuan He;Sienting Lau;Helen Laiwa Chan;Jintu Fan .High Dielectric Permittivity And Low Percolation Threshold In Nanocomposites Based On Poly(vinylidene Fluoride) And Exfoliated Graphite Nanoplates[J].Advanced Materials,2009(6):710-715. |
| [42] | Jiao YH;Xu JZ .Flame-Retardant Properties of Magnesium Hydroxystannate and Strontium Hydroxystannate Coated Calcium Carbonate on Soft Poly(vinyl chloride)[J].Journal of Applied Polymer Science,2009(1):36-43. |
| [43] | Wang, L;Dang, ZM .Carbon nanotube composites with high dielectric constant at low percolation threshold[J].Applied Physics Letters,2005(4):2903-1-2903-3-0. |
| [44] | Z.-M. Dang;L. Wang;Y. Yin;Q. Zhang;Q.-Q. Lei .Giant Dielectric Permittivities in Functionalized Carbon-Nanotube/ Electroactive-Polymer Nanocomposites[J].Advanced Materials,2007(6):852-857. |
| [45] | Shihai Zhang;Nanyan Zhang;Cheng Huang;Kailiang Ren;Qiming Zhang .Microstructure and Electromechanical Properties of Carbon Nanotube/ Poly(vinylidene fluoride — trifluoroethylene — chlorofluoro- ethylene) Composites[J].Advanced Materials,2005(15):1897-1901. |
| [46] | Caifei Han;Aijuan Gu;Guozheng Liang;Li Yuan .Carbon nanotubes/cyanate ester composites with low percolation threshold,high dielectric constant and outstanding thermal property[J].Composites, Part A. Applied science and manufacturing,2010(9):1321-1328. |
| [47] | Cheng Yang;Yuanhua Lin;C.W. Nan .Modified carbon nanotube composites with high dielectric constant, low dielectric loss and large energy density[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(4):1096-1101. |
| [48] | Sun, L.L.;Li, B.;Zhao, Y.;Mitchell, G.;Zhong, W.H. .Structure-induced high dielectric constant and low loss of CNF/PVDF composites with heterogeneous CNF distribution[J].Nanotechnology,2010(30):305702-1-305702-8. |
| [49] | ZHANG Q M;LI H F;POH M et al.An all organic composite actuator material with a high dielectric constant[J].Nature,2002,419(6904):284287. |
| [50] | XU H S;BAI Y;BHARTI V et al.High dielectric constant composites based on metallophthalocyanine oligomer and poly (vinylidene fluoride-tfifluorocthylene) copolymer[J].Journal of Applied Polymer Science,2001,82(01):70-75. |
| [51] | Cheng Huang;Q. M. Zhang;Gal deBotton;Kaushik Bhattacharya .All-organic dielectric-percolative three-component composite materials with high electromechanical response[J].Applied physics letters,2004(22):4391-4393. |
| [52] | Cheng Huang;Qiming Zhang .Fully Functionalized High-Dielectric-Constant Nanophase Polymers with High Electromechanical Response[J].Advanced Materials,2005(9):1153-1158. |
| [53] | WANG J W;SHEN Q D;YANG C Z et al.High dielectric constant composite of P(VDF-TrFE) with grafted copper phthalocyahine oligomer[J].Macromolecules,2004,37(06):2294-2298. |
| [54] | Wang, JW;Wang, Y;Wang, F;Li, SQ;Xiao, J;Shen, QD .A large enhancement in dielectric properties of poly(vinylidene fluoride) based all-organic nanocomposite[J].Polymer,2009(2):679-684. |
| [55] | Saha, R;Mandal, BK .New Copper Phthalocyanine Oligomers for High Dielectric Constant Polymer Films[J].Journal of Applied Polymer Science,2010(1):122-128. |
| [56] | High-dielectric-constant all-polymer percolative composites[J].Applied Physics Letters,2003(20):3502-3504. |
| [57] | Cheng Huang;Qiming Zhang .Enhanced Dielectric and Electromechanical Responses in High Dielectric Constant All-Polymer Percolative Composites[J].Advanced functional materials,2004(5):501-506. |
| [58] | Wang, CC;Song, JF;Bao, HM;Shen, QD;Yang, CZ .Enhancement of electrical properties of ferroelectric polymers by polyaniline nanofibers with controllable conductivities[J].Advanced Functional Materials,2008(8):1299-1306. |
| [59] | Jin-Kai Yuan;Zhi-Min Dang;Jinbo Bai .Unique dielectric properties in polyaniline/poly(vinylidene fluoride) composites induced by temperature variation[J].physica status solidi(RRL): rapid research letterse,2008(5):233-235. |
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