采用PI预聚体法合成硬质聚氨酯酰亚胺泡沫塑料,分析了发泡剂水对泡沫塑料密度、表面粉化程度以及力学性能的影响.运用幂次法则建立了力学性能与密度之间的关系,并利用体视显微镜和偏光显微镜对泡沫塑料的泡孔结构进行了研究.结果表明,硬质聚氨酯-酰亚胺泡沫塑料的密度、抗压强度与压缩模量、冲击强度以及泡孔棱厚随水用量的增加逐渐减小；孔径和表面粉化程度随水用量的增加而逐渐增大；密度与抗压强度、压缩模量、冲击强度之间的密度指数分别为1.78,1.55和0.72.
参考文献
| [1] | LEEST;PARKCB;RAMESHNS.Polymeric Foams:Science and Technology[M].New York:Taylor &.Francis Group,2007 |
| [2] | L. James Lee;Changchun Zeng;Xia Cao .Polymer nanocomposite foams[J].Composites science and technology,2005(15/16):2344-2363. |
| [3] | 齐锴亮,张广成,礼嵩明,刘良威.聚酰亚胺泡沫塑料的研究进展[J].材料导报,2011(07):67-70. |
| [4] | 李光珠,沈燕侠,詹茂盛.芳香族聚酰亚胺泡沫的隔热性能研究[J].材料工程,2009(07):43-46. |
| [5] | 乌云其其格,张连鸿,廖子龙.硬质泡沫塑料在航空结构中的应用[J].高科技纤维与应用,2009(03):41-44,56. |
| [6] | 周成飞,郭建梅,翟彤.聚（氨酯-酰亚胺）泡沫材料的研究[J].化工新型材料,2005(11):24-25. |
| [7] | SANG X M;CHEN X G;YU S W et al.Preparation and properties of rigid polyurethane-imide foams[J].Current Advances in Materials and Processes,2011,150-151:1119-1122. |
| [8] | SANG X M;WANG R Z;CHEN X G et al.Structure and compression properties of polyurethane-imide foams[J].Applied Mechanics andMaterials,2012,117 119:11171120. |
| [9] | Yeganeh H;Mehdipour-Ataei S;Ghaffari M .Preparation and properties of novel poly(urethane-imide)s via blending of reactive polyimide and epoxy-terminated urethane prepolymers[J].High performance polymers,2008(2):126-145. |
| [10] | LIU D;ZENG S;HU Q et al.Synthesis and properties of highly branched poly(urethane imide)via A2 + Ba approach[J].Polymer Bulletin,2010,64(09):877-890. |
| [11] | Qin XM;Yang XH;Wang XL;Wang MJ .Synthesis and characterization of poly(imide-urethane) based on novel chain-extender containing both imide and sulphone functions[J].Journal of Polymer Science, Part A. Polymer Chemistry,2005(19):4469-4477. |
| [12] | 秦秀敏,杨晓慧,王新灵,王铭钧.酰亚胺改性聚氨酯的合成和表征[J].上海交通大学学报,2006(07):1253-1256. |
| [13] | 周成飞,翟彤,曹巍,曾心苗,郭建梅.SiO2气凝胶/PUI复合硬泡的制备及其特性研究[J].橡塑技术与装备,2010(07):24-26. |
| [14] | SANG X M;CHEN X G;HOU G X et al.Preparation of rigid polyurethane-imide foams[J].Current Advances in Materials and Processes,2011,150-151:1123-1126. |
| [15] | Bibiao Jiang;Jianjun Hao;Wenyun Wang;Luxia Jiang;Xinxian Cai .Synthesis and thermal properties of poly(urethane-imide)[J].Journal of Applied Polymer Science,2001(3):773-781. |
| [16] | 詹茂盛,许小强,潘玲英.水发泡剂对聚酰亚胺泡沫结构与性能的影响[J].航空材料学报,2010(03):55-60. |
| [17] | W. Yamsaengsung .Effect of chemical blowing agent on cell structure and mechanical properties of EPDM foam, and peel strength and thermal conductivity of wood/NR composite-EPDM foam laminates[J].Composites, Part B. Engineering,2009(7):594-600. |
| [18] | NAJIB N N;ARIFF Z M;MANAN N A et al.Effect of blowing agent concentration on cell morphology and impact proper ties of natural rubber foam[J].Journal of Physical Science,2009,20(01):1325. |
| [19] | Zhu, B.;Zha, W.;Yang, J.;Zhang, C.;Lee, L.J. .Layered-silicate based polystyrene nanocomposite microcellular foam using supercritical carbon dioxide as blowing agent[J].Polymer: The International Journal for the Science and Technology of Polymers,2010(10):2177-2184. |
| [20] | 韩海军,丁雪佳,张丽娟,张德强,褚文娟,袁圆.水对硬质聚氨酯泡沫塑料性能的影响研究[J].工程塑料应用,2011(01):18-20. |
| [21] | 囤宏志,姜志国,王海侨,李效玉.戊二醛改性酚醛树脂及对泡沫塑料性能的研究[J].化工新型材料,2009(03):100-102. |
| [22] | 赵勐 .聚氨酯泡沫塑料/纳米SiO2复合材料的制备与研究[D].秦皇岛:燕山大学,2007. |
| [23] | Bo Yin;Zhong-Ming;Hui Quan;Qiu-Ming Zhou;Jian-Hua Wang .Morphology and Mechanical Properties of Nylon-1010-filled Rigid Polyurethane Foams[J].Journal of Elastomers & Plastics,2004(4):333-349. |
| [24] | 李小斌,曹宏斌,张懿.全水发泡硬质聚氨酯泡沫塑料技术研究进展[J].中国塑料,2004(07):1-4. |
| [25] | 马忠雷,张广成.泡沫塑料的微观结构与性能[J].工程塑料应用,2011(11):96-100. |
| [26] | GIBSON L J;ASHBY M F.Cellular Solids:Structure and Properties[M].Cambridge:Cambridge University Press,1997 |
| [27] | Thirumal M;Khastgir D;Singha NK;Manjunath BS;Naik YP .Effect of foam density on the properties of water blown rigid polyurethane foam[J].Journal of Applied Polymer Science,2008(3):1810-1817. |
| [28] | Yuan, J;Shi, SQ .Effect of the Addition of Wood Flours on the Properties of Rigid Polyurethane Foam[J].Journal of Applied Polymer Science,2009(5):2902-2909. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%